In these reactions, indicate the products M and N that are obtained (draw the formulas). Comment on each reaction briefly. O2N-CH3 + EtO-Na+, EtOH, 3 equivalents + CH2=CH-COOCH2CH3 → M (16 Carbons) M (16 Carbons) + H2 / Ni Raney → N (14 Carbons)
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- 1. Predict the elimination products of the following reactions. When two alkenes are possible, predict which one will be the major product. Explain your answers, showing the degree of substitution of each double bond in the products. 2. Which of these reactions are likely to produce both elimination and substitution products? (a) 2-bromopentane +NaOCH3 (b) 3-bromo-3-methylpentane +NaOMe(Me= methyl, CH3) (c) 2-bromo-3-ethylpentane +NaOH (d) cis-1-bromo-2-methylcyclohexane +NaOEt (Et= ethyl, CH2CH3)When 2-pentene is treated with Cl2 in methanol, three products are formed. Account for the formation of each product (you need not explain their relative percentages).name and draw the product/s formed from the reaction of 3-methylpent-2-ene: 1. with HBr 2. with Cl2 3. H2O in the presence of H2SO4 4. ethanol in the presence of H2SO4 5. Br2, H2O 6. [1] 9-BBN; [2] H2O2, OH-
- from the addition of one mole of HBr to one mole of Buten-1 is obtained: a) Bromo-1-butane b) bromine -2-butane c) Bromo-1,1-butane d) dibromo-2,2-butaneGive the major product for the reaction. (CH3)2CHCHBrCH3 + -OC(CH3)3Predict the major products of the following reactions, and propose mechanisms to support your predictions. (a) pent-1-ene + HCl(b) 2-methylpropene + HCl(c) 1-methylcyclohexene + HI(d) 4-methylcyclohexene + HBr
- For each reaction, show the generation of the electrophile and predict the products.(a) benzene + cyclohexene + HF (b) tert@butyl alcohol + benzene + BF3(c) tert@butylbenzene + 2@methylpropene + HFDraw structural formulas for the major product(s) formed by reaction of 3-hexyne with each of these reagents. (Where you predict no reaction, write NR.) Q.)Cl2 (1 mol)Choose 2 of the 3 compounds and provide a synthesis starting with benzene and any other carbon compound with four or less carbons.
- How would the following conversion be achieved? Please show the reaction mechanism step by stepAlkenes can be hydrated to form alcohols by (1) hydroboration followed by oxidation with alkaline hydrogen peroxide and (2) acid-catalyzed hydration. Compare the product formed from each alkene by sequence (1) with those formed from (2). Q.)CyclopenteneWrite the structure of the major organic product isolated from the reaction of 3-hexyne with (a) Hydrogen (2 mol), platinum (b) Hydrogen (1 mol), Lindlar palladium (c) Hydrogen chloride (1 mol) (d) Hydrogen chloride (2 mol) (e) Chlorine (1 mol) (f) Chlorine (2 mol) (g) Aqueous sulfuric acid, mercury(II) sulfate (h) Ozone followed by hydrolysis