Indicate how many stereoisomers are possible for each compound.    - square planar [Pt(NH3)Br22]:   - tetrahedral [NiClBr3]2−:   - octahedral [PtCl4Br2]2−:

Q: According to the selection rules, which ONE of the following coordination complexes will be LESS…

A: The colour is observed in a complex only when the transition take place in visible region Selection…

Q: The compound tris-(8-hydroxyquinolato)aluminum(III). Draw the structural isomers for this compound.…

A: Tris(8-hydroxyquinolinato)aluminium is the chemical compound with the formula Al(C9H6NO)3. Point…

Q: Chromium forms two common anionic carbonyl compounds: [Cr(CO)5]n- and [Cr(CO)4]m-. Deduce the…

A: The coordination compounds follows the EAN rule. To find the charge, first of all find the number of…

Q: While d-electrons in many transition metal compounds may not be involved directly in bond formation,…

A: While d-electrons in many transition metal compounds may not be involved directly in bond formation,…

Q: An optically active compound is composed of 75% of the (R) enantiomer and 25% of the (S) enantiomer.…

A: Answer

Q: Draw a structure for cis-dichlorobis(ethylenediamine)cobalt(III) ion. Is this ion chiral? Is the…

A: The species will be the chiral compound if they will not be superimposed in the mirror while if they…

Q: For any of the following that can exist as isomers, state thetype of isomerism and draw the…

A: a.

Q: 3-If two optically active compounds have the same Cotton effect: a) they have the same absolute…

A: If two optically active compounds have the same Cotton effect  = they have the same absolute…

Q: Rank the following complexes from smallest to largest d-orbital splitting i) [Fe(CN)6]³- ii)…

A:

Q: Which statement about the trans-effect and trans-influence is correct? a. The trans-influence is a…

A: We’ll answer the first question since the exact one wasn’t specified. Please submit a new question…

Q: 94. Carbon in cast iron 1. lowers its melting 2 increases its hardness and decrease its ductility 3.…

A: 94. D. Only 3 is correct.  Carbon in cast iron decreases its hardness and increases its ductility.…

Q: Which of the following compounds can exhibit cis-trans isomerism?   [Cr(H2O)6]3+ [Cu(CO)5Cl]+…

A:

Q: Draw the crystal-field energy-level diagrams for all compounds below: a)[Cr(H2O)6]2+ b)…

A:

Q: Find out the first row transition metals (M) for the following compounds (all of them obey 18e rule)…

A:

Q: Which of the following compounds are chiral? Br Br CH, HO HO Br Br OH но Br Br Br III IV

A: In compound II there is a plane of symmetry.in compound III there is not  a choral center as both…

Q: The reaction: Mn(CO)5(CH3) + CO → Mn(CO)5(COCH3) is an example of:   a. ligand addition   b.…

A: The given reaction of the Mn complex is: Mn(CO)5(CH3) + CO → Mn(CO)5(COCH3)

Q: Explain the difference between resolution of optical isomers and racemization?

A: Please find the differences:

Q: Which of the following compounds follow the effective atomic number rule, and which do not?(27Co,…

A: Effective atomic number rule is defined as the total number of electrons present around the central…

Q: true or false ?  The flowing compound is the amino acid glycine that contains glycinate bidentate…

A: The glycinate ion H2NCH2CO2- is formed by deprotonation of the amino acid glycine can function as a…

Q: Consider the given octahedral compounds: 1. Which of the compound/s do NOT have a Cz axis of…

A:

Q: Find out the first row transition metals (M) for the following compounds (all of them obey 18e rule)…

A: The 18 e- rule is used to predict the formula for stable metal complex. Also it can help in…

Q: Which of the following will exhibit cis-trans isomerism? Fe°: [Ar]4s²3d6 Cdº: [Kr]5s²4d10 Ptº:…

A: A multiple choice question based on coordination complex, which is to be accomplished.

Q: Draw the structures of the stereoisomers possible for [Co(NH3)4Cl2]Cl complex synthesized by Alfred…

A:

Q: What type of isomerism is exhibited by the following pair? NH₂ NO₂ H₂N H₂N O₂N H₂N NH3 O optical O…

A: Fac means Facial i.e. the same ligands form a common face of the polyhedron. Mer means Meridonial…

Q: Draw the structures of all possible isomers for the followingcomplexes. Indicate which isomers are…

A: The structures of all the isomers are given in the following steps.

Q: Q5 Below are the Period 4 transition metals. Indicate on the table: a) the element that forms an…

A: 18 electron rule  The 18 electron rule is used primarily for prediction and rationalizing formula…

Q: Which complex below is the MOST stable? O a. [FeCl2(NH3)2] O b. [TİCI2(NH3)2] O c. [MnCl2(NH3)2] O…

A: ANSWER: ANSWER 6. The complexes are most stable in which central atom  have d0, d5 and d10…

Q: Write the structures and names of all the stereoisomers of the following compounds :(i)…

A:

Q: 1. Consider the 18-rule as a guide and determine t complexes: i- Naz Fe(CO)n ii- MnBr(CO), iii-…

A:

Q: What type of isomerism is exhibited by the following pair? NH₂ CI H₂N, H₂N NH3 H₂N H₂N NH₂ NH₂…

A: Isomerism means two compounds having dame molecular formula but the different structural formula.

Q: [Co(CN):(OH;)J* + [Co(NH3)s(NCS)}* = [Co(CN):(SCN)]* + [Co(OH,);F* 3. Explain why, in the products…

A:

Q: When Cr(NH3)2(CO)4 undergoes ligand substitution, will the intermediate be associate or dissociative…

A: A question based on ligand substitution in coordination complex, which is to be accomplished.

Q: 80 B 60 40 20 400 500 600 700 Wavelength (nm) Absorption (%)

A: Two pigments and their absorption spectrum have been considered.

Q: Predict the R,S configurations for the labelled chiral centers:

A: The R,S configurations for the labeled chiral centres can be predicted as,

Q: If you were asked to assign the chirality center as R or S configuration for the molecule below,…

A:

Q: Which of the following complexes are chiral? 1: [Ru(ena2 II: [Pt(dien)C* II: cis-Cr(C2O4hCh]3- IV:…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: Write all the isomers of [PtCl(CO)(PMe3)(C2H4)]+ and use the trans directing effect of ligands to…

A: Isomers of [PtClCOPMe3C2H4]+

Q: 9a. The [Ir(en)3]3 cation can exhibit chiral properties. Draw the two non-superimposable isomers for…

A: [ Ir(en)3]+3 cation can exhibit chiral properties. Draw the non-superimposable isomer for this…

Q: Which complex below is the MOST stable? a. [FeCl2(NH3)2] O b. [Ticl2(NH3)2] O c. [MnCl2(NH3)2] O d.…

A: Crystal field stabilization energy is defined as difference in energy between t2g and eg set of…

Q: An optically active compound is composed of 75% of the (R) enantiomer and 25% of the (S) enantiomer.…

A: Enantiomers :-  A pair of optically active isomers which are non superimposable mirror images of…

Q: Calculate in units of deltaₒ, the LFSE for the octahedral ions below in their high-spins state.…

A: LFSE (Ligand Field Stabilisation Energy) is the measure of the stability of the complexes.

Q: Draw a complete molecular orbital diagram for 1,3,5,7-octatetraene including: Labeled y-axis. MO…

A:

Q: Which of the following are enantiomers of each other? Br B. OB, D OA, C O A, B OB, C A A Br Br HA C…

A:

Q: What is a possible product of the following reaction? OCH₂ AB Br A + Cl₂ OCH₂ OCH ₂ CI a d d Br CI…

A:

Q: 14.41 Label nonequivalent carbons in the following compounds. CHO OCH, OCH, CH,Q CH₂0 OCH, д

A:

Q: Classify the following reactions as oxidative addition, reductive elimination, (1,1 / 1,2)migratory…

A:

Q: Which of these molecules are optical active, explain your selections and draw the structure of the…

A: Given: (a) CH2Cl2 (b) NH2C1 (d) CCIBrHF

Q: Which of these complexes would have the greatest ∆O value? [CoF6]3- [CoCl6]3- [CoBr6]3-

A:

Q: Which of the following salts gives the following Ksp expression? Ksp = 108s5 a. Sn(OH)4 B.…

A: a. Sn(OH)2 Sn(OH)2 (s) ⇌ Sn2+ (aq) + 2 OH- (aq)                        s                   2s…

Q: Which of the following compounds are chiral? II II IV A I, IV, and V (B) Il and II II only D Il only…

A: Given compounds are : Options are : Which of the following compounds are chiral = ?