Which of the following complexes are chiral? 1: [Ru(ena2 II: [Pt(dien)C* II: cis-Cr(C2O4hCh]3- IV: trans-ICr(C3O4hCh]³- V: [Ca(OHab(NH3als O Only III O l and III O L Il and V Il and II Ol and IV

Q: The ligand-field strength also depends on the identity of the central ion, the order being Mn2+ <…

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Q: 3) Which of the following complexes are chiral? Draw the enantiomers of the complexes identified as…

A: From given  For each complexes initially identified whether it is chiral or achiral and if so it is…

Q: hirality in Four Coordinate Complexes ome coordination complexes are chiral. Just like in molecular…

A: We will assign chiral or achiral

Q: Do you expect any tetragonal distortion from octahedral structures of the following complexes.…

A: The Jahn Teller Effect is a geometric distortion of a non linear molecular system that reduces its…

Q: A transition metal, M, is coordinated in an octahedral fashion to the following ligands Two chloro…

A: We get a total of 6 Isomers.2 isomers where Cl atoms are trans.Since a sigma plane passes through…

Q: For this species below, state the point group НО HO. For this species below, state the point group…

A: In chelation hard centre prefers hard donor centre. Here Sulphur is soft donor , N is less harder…

Q: 19- Which of the two complexes [cu(NH3)4]*2 / [Cu(NH3)4]* Are they colored? Why?

A: NOTE: please note according to our policies , we can only answer one question at one time. you have…

Q: Which of the following pairs are coordination isomers? O A. [PtCl4(H2O)2]C12 and [PtCl3(H2O)2]Cl3 O…

A: coordination isomer : When both cation and anion are complex, in a coordination compound , then the…

Q: Upioad alse (a) Predict whether [Cr(H:O)]" complex is paramagnetic or diamagnetic using VBT. (b)…

A: Diamagnetic substances can be defined as the substances that contain paired electrons and do not…

Q: Q6.  a) which of these complexes [CoF6]3- and [Co(en)3]3+ Is high spin and how many unpaired…

A: Therefore, [CoF6]3- is a high spin complex , and there are 4 unpaired Electrons present in it.

Q: If the complex [W(C5H5)2(CO)2] follows the 18e rule, what is the hapticity of each (C5H5)? a. 5 and…

A: Hepticity explains the number of atoms from a ligand coordinate with central metal. Here, Tungsten…

Q: "Are all the organometallic complexes stable to moisture and temperature?" Explain.

A: the thermal stability organometallic compound generally decreases from the lightest to the heaviest…

Q: F3C-M ligand is a pi acceptor/ pi donor or neither?

A: pi acceptor ligands are those in which it have empty p orbitals and a good sigma donor. When bonding…

Q: Werner prepared two compounds by heating a solution of PtCl₂ with triethyl phosphine, P(C₂H₅)₃,…

A: From given percentage values the moles of each element is calculated as shown below, Pt moles=38.8g…

Q: Compounds with lone pair of electrons are able to form complexes via the donation of electrons…

A: To donate electrons pair, the molecule should have a negative charge or a lone pair of electrons.…

Q: Draw the geometry of: diquadiododdinitropalladium(IV) - and all its ligands trans

A: The complex given is diquadiododdinitropalladium(IV).

Q: [NİCI_(PPH3)2] is diamagnetic. On heating the complex became paramagnetic with a magnetic moment of…

A: The magnetic properties of the complex compounds depends on the electrons present in the d-orbital…

Q: Explain why the tetrahedral complexes A and B have magnetic moments of 1.89 and 0.0 BM respectively

A: Fe2+ is 3d6 It Has 0 unpaired electron in l.s. complexes and thus the magnetic moment would be close…

Q: Which of the following ions/ligands is highest in the spectrochemical series: CO, SO4-2, Br-, ox2-,…

A: Which one of the following is correct answer

Q: (c) Explain why C2 symmetrical ligands are found to give greater selectivity than unsymmetrical…

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Q: Characterize each of t Following CooXDivation comprends M₂₂ [Cr CH₂)₂ (CN)+] [M(NH3)3 Brolls…

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Q: Determine the number of stereoisomers for square-planar metal complex: [PtCl2(en)]? en…

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Q: 3. Which complex shows lower C-O stretching frequency, [Ni(acac)2(H2O2 or [Ni(acac)2]? Explain.

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Q: Q1 a) which of these complexes [CoFs]³-and [Co(en);]+ Is high spin and how many unpaired electron…

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Q: Arrange these complexes in order of octahedral splitting energy, A.. Largest A. Smallest Ao Answer…

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Q: Consider the following complexes: [FeCl6]3- and [Fe(CN)6]3-, which possess very different magnetic…

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Q: Assign point groups to the two coordination complexes shown below. Give your reasoning/explanation…

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Q: Which orbital is LUMO in the molecular orbital diagram drawn for the sigma interaction of the…

A: As there is six mano dented ligands are there . Thus it is octahedral complex.  Where every mano…

Q: (b) Give the coordination geometries for each complexes. i. Re (CO) (p-n-C,H) ii. (Ar)W(CO)s iii.…

A: The required work is attached here , kindly find

Q: For which member of the following pairs of complexes would A. be larger and why? i [Cr(H:O)k]* and…

A: By comparing ligand field strength and central metal ion we can decide the value of Δo for a…

Q: 5) Rank the following sigma complexes in order of increasing stability. H **$$ Br Br H NO₂ + A H Br…

A: Given:

Q: Draw a Lewis structure for the cyclopentadienyl ligand (C5H5)- and explain why it is more likely to…

A: Cyclopentadienyl anion ligand, (C5H5)-, it is formed by the deprotonation of cyclopentadiene,…

Q: In each the following generalized coordination complexes, M represents the central metal ion and L1,…

A: From given  Enantiomers are optical isomers which are mirror images to each other so we are finding…

Q: Predict the d orbital splitting of [RuCl6]2-complex. A) (t2g)2(eg)3 B) (t2g)4(eg)2 C) (t2g)3(eg)1…

A: Complex = [RuCl6]2- In this complex, Ru present in +4 oxidation state.  Electronic configuration of…

Q: SAIC Pr7.1 The compound Na,lrCl, reacts with triphenylphosphine in diethyleneglycol in an atmosphere…

A: Isomers are compounds with same molecular formula but different structural formula.…

Q: SAIC Pr7.1 The compound Na,IrCl reacts with triphenylphosphine in diethyleneglycol in an atmosphere…

A: Isomers are compounds with same molecular formula but different structural formula.  In a trigonal…

Q: Consider the reactions below. Which of the following correctly identifies the coordinate complex?…

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Q: Foreach of the following pairs of complexes, identify the one that has the larger Crstal Field…

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Q: Which coordination complex has the greatest A,? O [ScI,j³- O [Sc(NH,),J³+ O [Sc(H,O),J³* O…

A: Given  Complex = [ ScI6 ]3- , [ Sc ( NH3 )6 ]3+  , [ Sc( H2O)6 ]3+ , [ Sc ( en )3 ]3+ ∆0  = ?

Q: 5 Which of the following complexes exhibits linkage isomerism? [Pt(NO)₂(NO3)2] [NiBr₂(en)₂]…

A: The isomers which have same molecular formula but differ in the linkage of ligand atom to the…

Q: SAIC Pr7.1 The compound Na,lrCl, reacts with triphenylphosphine in diethyleneglycol in an atmosphere…

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Q: When the ligand (H2SB-1) is deprotonated by the addition of triethylamine, SB-1²- is formed and is a…

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Q: Consider a d5 complex in tetrahedral symmetry. The dipole moment is found to be 1.73 μB. Is the…

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Q: i, d electron configuration ii crystal field theory summary i high/low-spin assignment based on…

A: (i)d electron configuration  Electronic configuration = (n-1)d1-10ns1-2 the element of d block have…

Q: Which of the following ligands is ambidentate? Select one or more: a. N3- b. SO42- c. SO32- d. SCN-

A: Ambient ligands : Such ligands have two or more donor atoms but only one donor atom is attached to…

Q: (g (n' (h M(n-CSH5):(CO)(M=M bond) 3 Calculate the Total Valence Electron (TVE) and sketch the…

A: Total valence electrons of a complex is equals to the valence electron of metal (d + s electrons)…

Q: Q5. (i) pentacarbonyl complex with (1) a primary amine, NH2R', and (2) a secondary amine, NHR'2.…

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Q: Chemistry Which of the following complexes are chiral? Give a brief justification of your reasoning…

A: Chiral Complex :                                     In chemistry, a molecule or ion is called…

Q: 6. Write the furmula of the following Complexes a. Dibromotctra avmmineruthemum (1) nitrak b.…

A: Note : As per our guidelines we are supposed to answer only one question .please resubmit the 7th…

Atomic Structure

The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.

Shape of the D Orbital

Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.