Indicate using true or false for each of the following statements: 1. pKa always larger than pKb.  2. The higher pKa the higher acidity..  3. pKw always equal to 10-^14.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter14: Equilibria In Acid-base Solutions
Section: Chapter Questions
Problem 34QAP: A buffer is prepared using the butyric acid/butyrate (HC4H7O2/C4H7O2)acid-base pair. The ratio of...
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Indicate using true or false for each of the following statements:

1. pKa always larger than pKb. 

2. The higher pKa the higher acidity.. 

3. pKw always equal to 10-^14. 

4. Compounds might have more than pKa. 

5. We usually prefer to prepare buffers from alkaline origin compounds. 

6. The pH of a buffer solution containing .1 M acetic acid and 0.1 M sodium acetate? (Ka for acetic acid = 1.75 ×10-5) is 3.9. 

7. The pH of a solution containing ephedrine 0.1 M and ephedrine HCI 0.01 M? (Kb for ephedrine = 2.3 x 10-5) is 7.99. 

8. The maximum buffer capacity for solutions can be achieved when the required pH double than pKa of the acid.. 

9. When one of the buffer components is depleted completely the solution lose its buffering capacity and can no longer resist the change in pH. 

10. At a hydrogen ion concentration of 1.75 x 10-5, what is the capacity of a buffer containing 0.10 mole each of acetic acid and sodium acetate per liter of solution? (Ka = 1.75 x 10-5 ) is 9.11.

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