Indicate your predictions beneath the reaction (using one the following symbols →, ←, ↓, ↑ where appropriate) following the application of stress to the equilibrium reactions: Part I: On treatment with sodium acetate predict if the pH increases (↑) or decreases (↓).  CH3COOH(l) +H2O(l) -><- CH3COO-(aq) + H3O+ (aq) Part II: On treatment with concentrated HCl which direction will the equilibrium adjust to minimize the “stress”: Shift left (←) or right (→)? 2H+ (aq) + 2CrO42- (aq) -><- CR2O72- (aq) + H2O (l) Part III: An equilibrium system consisting of BiCl3 and bismuth hypochlorite in water was treated with H2O. Which direction will the equilibrium adjust to minimize the “stress”: Shift left (←) or right (→)? BiCl3(s) + H2O(l) -><- BiOCl(s) + 2Cl-(aq) + 2H+ (aq)

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter4: Acids And Bases
Section: Chapter Questions
Problem 4.10P: Complete a net ionic equation for each proton-transfer reaction using curved arrows to show the flow...
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Indicate your predictions beneath the reaction (using one the following symbols →, ←, ↓, ↑ where appropriate) following the application of stress to the equilibrium reactions:


Part I: On treatment with sodium acetate predict if the pH increases (↑) or decreases (↓). 

CH3COOH(l) +H2O(l) -><- CH3COO-(aq) + H3O+ (aq)

Part II: On treatment with concentrated HCl which direction will the equilibrium adjust to minimize the “stress”: Shift left (←) or right (→)?
2H+ (aq) + 2CrO42- (aq) -><- CR2O72- (aq) + H2O (l)


Part III: An equilibrium system consisting of BiCl3 and bismuth hypochlorite in water was treated with H2O. Which direction will the equilibrium adjust to minimize the “stress”: Shift left (←) or right (→)?

BiCl3(s) + H2O(l) -><- BiOCl(s) + 2Cl-(aq) + 2H+ (aq)


Part IV: On treatment with concentrated HCl which direction will the equilibrium adjust to minimize the “stress”: Shift left (←) or right (→)?

[Co(H2O)6]2+(aq) + 4Cl- (aq) <-> [CoCl4]2-(aq) + 6H2O(l)


Part V: On treatment with 6 M NaOH which direction will the equilibrium adjust to minimize the “stress” Shift left (←) or right (→)?

Fe3+ (aq) SCN- (aq) <-> [Fe(SCN)]2+(aq)


Part VI: What is the function of the vacuum aspirator? Predict the color shift of the indicator as a consequence of the applied “stress”.

Originally greenish-yellow because of 1M of HCL added. 

HCO3-(aq) <-> CO2(g) + OH- (aq)

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