IR Spectrum (KBr disc) 4000 100 80 ................ % of base peak 10 3000 20 40 80 13C NMR Spectrum (50.0 MHz, CDCI, solution) 59 9 DEPT CH₂ CH₂ CH proton decoupled 200 ¹H NMR Spectrum (200 MHz. CDCI, solution) 101 exchanges with D₂O 11.0 2000 120 V (cm¹) 1722 1680 1600 142 160 160 m/e Amer 1200 M+160 (<1%) 800 Mass Spectrum 120 200 240 280 solvent 80 4 C7H1204 10.0 ppm 8 7 6 5 No significant UV absorption above 220 nm 40 3 2 08 (ppm) TMS 0 8 (ppm) 1

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter17: Alcohols And Phenols
Section17.SE: Something Extra
Problem 53AP: Propose a structure consistent with the following spectral data for a compound C8H18O2: IR: 3350...
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Analyze all spectrum and identify the compound
IR Spectrum
(KBr disc)
4000
100
80
60
40
20
40
13C NMR Spectrum
(50.0 MHz, CDCI, solution)
% of base peak
10
3000
9
59
83
DEPT CH₂ CH₂ CH
proton decoupled
200
¹H NMR Spectrum
(200 MHz, CDCI, solution)
11.0
80
101
exchanges
with D₂O
8
2000
120
V (cm¹)
142
1722 1680
1600
160
Amo
1200
m/e
10.0 ppm
M+160 (1%)
160
800
Mass Spectrum
120
200 240 280
C7H1204
7 6 5
solvent
80
4
No significant UV
absorption above 220 nm
40
3 2
0 8 (ppm)
TMS
8 (ppm)
1
Transcribed Image Text:IR Spectrum (KBr disc) 4000 100 80 60 40 20 40 13C NMR Spectrum (50.0 MHz, CDCI, solution) % of base peak 10 3000 9 59 83 DEPT CH₂ CH₂ CH proton decoupled 200 ¹H NMR Spectrum (200 MHz, CDCI, solution) 11.0 80 101 exchanges with D₂O 8 2000 120 V (cm¹) 142 1722 1680 1600 160 Amo 1200 m/e 10.0 ppm M+160 (1%) 160 800 Mass Spectrum 120 200 240 280 C7H1204 7 6 5 solvent 80 4 No significant UV absorption above 220 nm 40 3 2 0 8 (ppm) TMS 8 (ppm) 1
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