IR spectrum (Nujol mull), pmr, mass and ¹3C spectra of a compound having a molecular weight of 135.0685. UV absorption observed. 4000 3200 3600 2800 2400 1800 2000 1600 1400 1200 800 1000 600 -100 30

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter12: Structure Determination: Mass Spectrometry And Infrared Spectroscopy
Section12.SE: Something Extra
Problem 48AP: The infrared spectrum of the compound with the mass spectrum shown below lacks any significant...
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Assign structure, with explanations, to the given spectrum of IR, MS, 1HNMR and 13CNMR

IR spectrum (Nujol mull), pmr, mass and ¹³C spectra of a compound having
a molecular weight of 135.0685. UV absorption observed.
4000 3600
2800
3200
1800
4000
199
$3
80
28
18
70
60
9
30
40
3600 3200 2800
2
BAN
00
HIIH
WWLE
2400
2400
3
2000
2000 1800
1400
1600
1600
(a) IR Spectrum
(6)
MY
A
1000
1200
6
1200
1400
1000
1
8
B00
BUIHI
600
800
600
CHIENMER.
431
400
abundance
4100
MS
.30
0 10 20 30 40 50
CMR
230 210 190
170
150
60
70 80 90 100 110 120 130 140 150
(c) M/2
130
(d)
110 90
27.3q
114.3d
126.8s
132.3d
155.1s
196.9s
70
T
50
homman
30
10 0
Transcribed Image Text:IR spectrum (Nujol mull), pmr, mass and ¹³C spectra of a compound having a molecular weight of 135.0685. UV absorption observed. 4000 3600 2800 3200 1800 4000 199 $3 80 28 18 70 60 9 30 40 3600 3200 2800 2 BAN 00 HIIH WWLE 2400 2400 3 2000 2000 1800 1400 1600 1600 (a) IR Spectrum (6) MY A 1000 1200 6 1200 1400 1000 1 8 B00 BUIHI 600 800 600 CHIENMER. 431 400 abundance 4100 MS .30 0 10 20 30 40 50 CMR 230 210 190 170 150 60 70 80 90 100 110 120 130 140 150 (c) M/2 130 (d) 110 90 27.3q 114.3d 126.8s 132.3d 155.1s 196.9s 70 T 50 homman 30 10 0
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