Is each of these statements true? If not, explain why.(a) At a given T, all molecules have the same kinetic energy.(b) Halving the Pof a gaseous reaction doubles the rate.(c) A higher activation energy gives a lower reaction rate.(d) A temperature rise of 10°C doubles the rate of any reaction.(e) If reactant molecules collide with greater energy than theactivation energy, they change into product molecules.(f ) The activation energy of a reaction depends on temperature.(g) The rate of a reaction increases as the reaction proceeds.(h) Activation energy depends on collision frequency.(i) A catalyst increases the rate by increasing collision frequency.( j) Exothermic reactions are faster than endothermic reactions.(k) Temperature has no effect on the frequency factor (A).(l) The activation energy of a reaction is lowered by a catalyst.(m) For most reactions, ΔH°ᵣₓₙ is lowered by a catalyst.(n) The orientation probability factor (p) is near 1 for reactions between single atoms.(o) The initial rate of a reaction is its maximum rate.(p) A bimolecular reaction is generally twice as fast as a uni-molecular reaction.(q) The molecularity of an elementary reaction is proportional to the molecular complexity of the reactant(s).

Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Chapter12: Kinetics
Section: Chapter Questions
Problem 65E: The hydrolysis of the sugar sucrose to the sugars glucose and fructose, C12H22O11+H2OC6H12O6+C6H12O6...
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Is each of these statements true? If not, explain why.(a) At a given T, all molecules have the same kinetic energy.(b) Halving the Pof a gaseous reaction doubles the rate.(c) A higher activation energy gives a lower reaction rate.(d) A temperature rise of 10°C doubles the rate of any reaction.(e) If reactant molecules collide with greater energy than theactivation energy, they change into product molecules.(f ) The activation energy of a reaction depends on temperature.(g) The rate of a reaction increases as the reaction proceeds.(h) Activation energy depends on collision frequency.(i) A catalyst increases the rate by increasing collision frequency.( j) Exothermic reactions are faster than endothermic reactions.(k) Temperature has no effect on the frequency factor (A).(l) The activation energy of a reaction is lowered by a catalyst.(m) For most reactions, ΔH°ᵣₓₙ is lowered by a catalyst.(n) The orientation probability factor (p) is near 1 for reactions between single atoms.(o) The initial rate of a reaction is its maximum rate.(p) A bimolecular reaction is generally twice as fast as a uni-molecular reaction.(q) The molecularity of an elementary reaction is proportional to the molecular complexity of the reactant(s).

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