Lead(II) carbonate, also called "white lead, was formerly used as a pigment in white paints. However, because of its toxicity, lead can no longer be used in paints intended for residential homes. Lead(II) carbonate is prepared industrially by reaction of aqueous lead(II) acetate with carbon dioxide gas. The unbalanced equation is Pb(C2H3 O2), (aq) + H2O(1) + CO2 (9) → PBCO3(s) + HC,H3 O2 (aq) Suppose an aqueous solution containing 1.25 g of lead(II) acetate is treated with 5.95 g of carbon dioxide. Calculate the theoretical yield of lead carbonate.

Lead(II) carbonate, also called "white lead, was formerly used as a pigment in white paints. However, because of its toxicity, lead can no longer be used in paints intended for residential homes. Lead(II) carbonate is prepared industrially by reaction of aqueous lead(II) acetate with carbon dioxide gas. The unbalanced equation is Pb(C2H3 O2), (aq) + H2O(1) + CO2 (9) → PBCO3(s) + HC,H3 O2 (aq) Suppose an aqueous solution containing 1.25 g of lead(II) acetate is treated with 5.95 g of carbon dioxide. Calculate the theoretical yield of lead carbonate.

Chemistry for Engineering Students

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Chapter4: Stoichiometry

Section: Chapter Questions

Problem 4.91PAE

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A power plant is driven by the combustion of a complex fossil fuel having the formula C11H7S. Assume the air supply is composed of only N2 and O2 with a molar ratio of 3.76:1.00, and the N2 remains unreacted. In addition to the water produced, the fuels C is completely combusted to CO2 and its sulfur content is converted to SO2. In order to evaluate gases emitted at the exhaust stacks for environmental regulation purposes, the nitrogen supplied with the air must also be included in the balanced reactions. a Including the N2 supplied m the air, write a balanced combustion equation for the complex fuel assuming 100% stoichiometric combustion (i.e., when there is no excess oxygen in the products and the only C-containing product is CO2). Except in the case of N2, use only integer coefficients. b Including N2 supplied in the air, write a balanced combustion equation for the complex fuel assuming 120% stoichiometric combustion (i.e., when excess oxygen is present in the products and the only C-containing product is CO2). Except in the case of use only integer coefficients c Calculate the minimum mass (in kg) of air required to completely combust 1700 kg of C11H7S. d Calculate the air/fuel mass ratio, assuming 100% stoichiometric combustion. e Calculate the air/fuel mass ratio, assuming 120% stoichiometric combustion.
4.69 The pictures below show a molecular-scale view of a chemical reaction between H2 and CO to produce methanol, CH3OH. The box on the left represents the reactants at the instant of mixing, and the box on the right shows what is left once the reaction has gone to completion. Was there a limiting reactant in this reaction? If so, what was it? Write a balanced chemical equation for this reaction. As usual, your equation should use the smallest possible whole number coefficients for all substances.
3.18 Diborane and related compounds were proposed as rocket fuels in the 1950s. A representative reaction for this class of molecules is that of B2H6 and O2 to form B2O3 and H2O. Write the balanced chemical equation for this process.
3.91 Hydrogen cyanide (HCN) is extremely toxic, but it is used in the production of several important plastics. In the most common method for producing HCN, ammonia (NH3) and methane (CH4) react with oxygen (O2) to give HCN and water. Write a balanced chemical equation for this reaction. Hydrogen cyanide, HCN
Many cereals are made with high moisture content so that the cereal can be formed into various shapes before it is dried. A cereal product containing 58% H2O by mass is produced at the rate of 1000. kg/h. What mass of water must be evaporated per hour if the final product contains only 20.% water?
The space shuttle environmental control system handles excess CO2 (which the astronauts breathe out; it is 4.0% by mass of exhaled air) by reacting it with lithium hydroxide, LiOH, pellets to form lithium carbonate, Li2CO3, and water. If there are seven astronauts on board the shuttle, and each exhales 20. L of air pee minute, how long could clean air be generated if there were 25,000 g of LiOH pellets available for each shuttle mission? Assume the density of air is 0.0010 g/mL.
Bacterial digestion is an economical method of sewage treatment. The reaction is an intermediate step in the conversion of the nitrogen in organic compounds into nitrate ions. What mass of bacterial tissue is produced in a treatment plant for every 1.0 104 kg of wastewater containing 3.0% NH4+ ions by mass? Assume that 95% of the ammonium ions are consumed by the bacteria.
4.21 Ammonium nitrate, NH4NO3, will decompose explosively to form N2, O2, and H2O, a fact that has been exploited in terrorist bombings. What mass of nitrogen is formed by the decomposition of 2.6 kg of ammonium nitrate?
3.87 Nitric acid (HNO3) can be produced by the reaction of ni- trogen dioxide (NO2) and water. Nitric oxide (NO) is also formed as a product. Write a balanced chemical equation for this reaction.
4.72 The picture shown depicts the species present at the start of a combustion reaction between methane, CH4 and oxygen, O2 (a) What is the limiting reactant? (b) Draw the resulting state after this set of reactants has reacted as far as possible.
3.50 A test of an automobile engine's exhaust revealed that g of NO2 was emitted in 10 minutes of operation. How many moles of NO2 would this engine release if it were used for a 45-minute commute, assuming that this mea- sured number is representative of the emission under all circumstances?
89 A number of compounds containing the heavier noble gases, and especially xenon, have been prepared. One of these is xenon hexafluoride (XeF6), which can be prepared by heating a mixture of xenon and fluoride gases. XeF6 is a white crystalline solid at room temperature and melts at about 325 K. A mixture of 0.0600 g of Xe and 0.0304 g of F2 is sealed into a 100.0-mL bulb. (The bulb is heated, and the reaction goes to completion. Then the sealed bulb is cooled back to 20.0°C. What will be the final pressure in the bulb, expressed in torr?

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