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- A metallic container of fixed volume of 2.5103 m3 immersed in a large tank of temperature 27 contains two compartments separated by a freely movable wall. Initially, the wall is kept in place by a stopper so that there are 0.02 mol of the nitrogen gas on one side and 0.03 mol of the oxygen gas on the other side, each occupying half the volume. When the stopper is removed, the wall moves and comes to a final position. The movement of the wall is controlled so that the wall moves in infinitesimal quasi-static steps. (a) Find the final volumes of the two sides assuming the ideal gas behavior for the two gases. (b) How much work does each gas do on the other? (c) What is the change in the internal energy of each gas? (d) Find the amount of heat that enters or leaves each gas.Which of the assumptions below is not made in the kinetic theory of gases? (a) The number of molecules is very large. (b) The molecules obey Newtons laws of motion. (c) The forces between molecules are long range. (d) The gas is a pure substance. (e) The average separation between molecules is large compared to their dimensions. (f) of (his account are correct statements necessary for a clear and complete explanation? (ii) Which are correct statements that are not necessary to account for the higher thermometer reading? (iii) Which are incorrect statements?One cylinder contains helium gas and another contains krypton gas at the same temperature. Mark each of these statements true, false, or impossible to determine from the given information. (a) The rms speeds of atoms in the two gases are the same. (b) The average kinetic energies of atoms in the two gases are the same. (c) The internal energies of 1 mole of gas in each cylinder are the same. (d) The pressures in the two cylinders ale the same.
- Consider the Maxwell-Boltzmann distribution function plotted in Problem 28. For those parameters, determine the rms velocity and the most probable speed, as well as the values of f(v) for each of these values. Compare these values with the graph in Problem 28. 28. Plot the Maxwell-Boltzmann distribution function for a gas composed of nitrogen molecules (N2) at a temperature of 295 K. Identify the points on the curve that have a value of half the maximum value. Estimate these speeds, which represent the range of speeds most of the molecules are likely to have. The mass of a nitrogen molecule is 4.68 1026 kg. Equation 20.18 can be used to find the rms velocity given the temperature, Boltzmanns constant, and the mass of the atom or molecule. The mass of a nitrogen molecule is 4.68 1026 kg. vrms=3kBTm=3(1.381023J/K)4.681026kg=511m/s Using the results of Problem 28 and the rms velocity, we can calculate the value of f(v). f(vrms) = (3.11 108)(511)2 e(5.75106(511)2) = 0.00181 The most probable speed, for which this function has its maximum value, is given by Equation 20.20. vmp=2kBTm=2(1.381023J/K)(295K)4.681026kg=417m/s f(vmp) = (3.11108)(417)2 e(5.75106(417)2) = 0.00199 We plot these points on the speed distribution. The most probable speed is indeed at the peak of the distribution function. Since the function is not symmetric, the rms velocity is somewhat higher than the most probable speed. Figure P20.29ANSA sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P21.65). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state, (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally, (f) Find Q, W, and Eint for each of the processes, (g) For the whole cycle A B C A, find Q, W, and Eint.A gas in a cylindrical closed container is adiabatically and quasi-statically expanded from a state A (3 MPa, 2 L) to a state B with volume of 6 L along the path 1.8pV= constant. (a) Plot the path in the pV plane. (b) Find the amount of work done by the gas and the change in the internal energy of the gas during the process.
- (a) People often think of humid air as "heavy." Compare the densities of air with 0% relative humidity and 100% relative humidity when both are at 1 atm and 30 . Assume that the dry air is an ideal gas composed of molecules with a molar mass of 29.0 g/mol and the moist air is the same gas mixed with water vapor. (b) As discussed in the chapter on the applications of Newton's laws, the air resistance felt by projectiles such as baseballs and golf balls is approximately FD=CpAv2/2 , where p is the mass density of the air, A is the cross-sectional area of the projectile, and C is the projectile's drag coefficient. For a fixed air pressure, describe qualitatively how the range of a projectile changes with the relative humidity. (c) When a thunderstorm is coming, usually the humidity is high and the air pressure is low. Do those conditions give an advantage or disadvantage to home-run hitters?Compare the charge in internal energy of an ideal gas for a quasi-static adiabatic expansion with that for a quasi-static isothermal expansion. What happens to the temperature of an ideal gas in an adiabatic expansion?A sample of a monatomic ideal gas occupies 5.00 L at atmospheric pressure and 300 K (point A in Fig. P17.68). It is warmed at constant volume to 3.00 atm (point B). Then it is allowed to expand isothermally to 1.00 atm (point C) and at last compressed isobarically to its original state. (a) Find the number of moles in the sample. Find (b) the temperature at point B, (c) the temperature at point C, and (d) the volume at point C. (e) Now consider the processes A B, B C, and C A. Describe how to carry out each process experimentally. (f) Find Q, W, and Eint for each of the processes. (g) For the whole cycle A B C A, find Q, W, and Eint. Figure P17.68
- In a quasi-static isobaric expansion. 500 J of work are done by the gas. If the gas pressure is 0.80 atm, what is the fractional increase in the volume of the gas, assuming it was originally at 20.0 L?Two containers hold an ideal gas at the same temperature and pressure. Both containers hold the same type of gas, but container B has twice the volume of container A. (i) What is the average translational kinetic energy per molecule in container B? (a) twice that of container A (b) the same as that of container A (c) half that of container A (d) impossible to determine (ii) From the same choices, describe the internal energy of the gas in container B.The pressure gauge on a cylinder of gas registers the gauge pressure, which is the difference between the interior pressure and the exterior pressure P0. Lets call the gauge pressure Pg. When the cylinder is full, the mass of the gas in it is mi at a gauge pressure of Pgi. Assuming the temperature of the cylinder remains constant, show that the mass of the gas remaining in the cylinder when the pressure reading is Pgf is given by mf=mi(Pgf+P0Pgi+P0)