For this step of the synthesis, draw the arrow pushing mechanism for the following reaction. Include stereochemistry. Me^CO2MeМеCO2ME1,4-Benzoquinone, Pd(OAc)2HМе.,МеCNMe.,,-OTMSRT, 6 h, 80% (2 steps)See the Saegusa-Ito Oxidation"The yield was 89 % brsm."MeMeМеMe

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Answered: Me ^CO2Me Ме CO2ME 1,4-Benzoquinone,…

Me ^CO2Me Ме CO2ME 1,4-Benzoquinone, Pd(OAc)2 H Ме., МеCN Me.,, -OTMS RT, 6 h, 80% (2 steps) See the Saegusa-Ito Oxidation "The yield was 89 % brsm." Me Me Ме Me

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter7: Statistical Data Treatment And Evaluation

Section: Chapter Questions

Problem 7.9QAP

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Concept explainers

Polymerization Kinetics

Polymerization is a chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that diverge in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes. Polymerization is generally classified into step-growth and chain polymerization. Polymers are categorized into linear polymer and cross-linked polymers that are produced either by condensation or additional polymerization.

Question

For this step of the synthesis, draw the arrow pushing mechanism for the following reaction. Include stereochemistry.

Me
^CO2Me
Ме
CO2ME
1,4-Benzoquinone, Pd(OAc)2
H
Ме.,
МеCN
Me.,,
-OTMS
RT, 6 h, 80% (2 steps)
See the Saegusa-Ito Oxidation
"The yield was 89 % brsm."
Me
Me
Ме
Me

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