Metal sulfides are prepared by bubbling hydrogen sulfide gas, H,S, through an aqueous solution containing the metal ion, and then adjusting the pH. When the solution is saturated with H, S, which occurs when [H, S] = 0.100 M, the equilibrium shown is established. H,S(aq) + 2 H,O(1) = s²-(aq) + 2 H,0*(aq) Keq = 1.1 x 10-20 An aqueous solution containing 0.0331 M Zn2+ and 0.0331 M Ag+ is saturated with H, S. Above what concentration of S2- will ZnS precipitate? The Ksp of ZnS is 2.0 x 10-25. [s²-] M Above what concentration of S2- will Ag, S precipitate? The Ksp of Ag, S is 3.3 x 10-50. [s*-] = M

Chemistry & Chemical Reactivity
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Chapter17: Principles Of Chemical Reactivity: Other Aspects Of Aqueous Equilibria
Section17.6: Equilibria Involving Complex Ions
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Metal sulfides are prepared by bubbling hydrogen sulfide gas, H, S, through an aqueous solution containing the metal ion, and
then adjusting the pH. When the solution is saturated with H, S, which occurs when [H, S] = 0.100 M, the equilibrium shown
is established.
H, S(aq) + 2 H, O(1) = s2-(aq) + 2 H,O*(aq)
Keq
1.1 x 10-20
An aqueous solution containing 0.0331 M Zn2+ and 0.0331 M Ag+ is saturated with H, S. Above what concentration of S2- will
ZnS precipitate? The Ksp of ZnS is 2.0 × 10-25.
[s²-] =
M
Above what concentration of S2- will Ag, S precipitate? The Ksp of Ag, S is 3.3 x 10-50.
[s²-] =
M
Transcribed Image Text:Metal sulfides are prepared by bubbling hydrogen sulfide gas, H, S, through an aqueous solution containing the metal ion, and then adjusting the pH. When the solution is saturated with H, S, which occurs when [H, S] = 0.100 M, the equilibrium shown is established. H, S(aq) + 2 H, O(1) = s2-(aq) + 2 H,O*(aq) Keq 1.1 x 10-20 An aqueous solution containing 0.0331 M Zn2+ and 0.0331 M Ag+ is saturated with H, S. Above what concentration of S2- will ZnS precipitate? The Ksp of ZnS is 2.0 × 10-25. [s²-] = M Above what concentration of S2- will Ag, S precipitate? The Ksp of Ag, S is 3.3 x 10-50. [s²-] = M
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