Metal sulfides are prepared by bubbling hydrogen sulfide gas, H,S, through an aqueous solution containing the metal ion, and then adjusting the pH. When the solution is saturated with H, S, which occurs when [H, S] = 0.100 M, the equilibrium shown is established. H,S(aq) + 2 H,O(1) = s²-(aq) + 2 H,0*(aq) Keq = 1.1 x 10-20 An aqueous solution containing 0.0331 M Zn2+ and 0.0331 M Ag+ is saturated with H, S. Above what concentration of S2- will ZnS precipitate? The Ksp of ZnS is 2.0 x 10-25. [s²-] M Above what concentration of S2- will Ag, S precipitate? The Ksp of Ag, S is 3.3 x 10-50. [s*-] = M
Metal sulfides are prepared by bubbling hydrogen sulfide gas, H,S, through an aqueous solution containing the metal ion, and then adjusting the pH. When the solution is saturated with H, S, which occurs when [H, S] = 0.100 M, the equilibrium shown is established. H,S(aq) + 2 H,O(1) = s²-(aq) + 2 H,0*(aq) Keq = 1.1 x 10-20 An aqueous solution containing 0.0331 M Zn2+ and 0.0331 M Ag+ is saturated with H, S. Above what concentration of S2- will ZnS precipitate? The Ksp of ZnS is 2.0 x 10-25. [s²-] M Above what concentration of S2- will Ag, S precipitate? The Ksp of Ag, S is 3.3 x 10-50. [s*-] = M
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter17: Principles Of Chemical Reactivity: Other Aspects Of Aqueous Equilibria
Section17.6: Equilibria Involving Complex Ions
Problem 2.1ACP: Phosphate ions are abundant in cells, both as the ions themselves and as important substituents on...
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