Molecular Formula: C4H₂N₂O4 TEST/REAGENT(S) Br2, dark [Ag(NH3)2]NO3 2,4-DNPH Test ZnCl₂, HCI VISIBLE RESULT Red orange solution Colorless solution Yellow-orange precipitate No formation of layers INFERENCE (1) Not an alkyne (2) (3)

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter14: Applications Of Ultraviolet-visible Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 14.21QAP
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Molecular Formula: C4H₂N2O4
TEST/REAGENT(S)
Brz, dark
[Ag(NH3)2]NO3
2,4-DNPH Test
ZnCl₂, HCI
Neutral KMnO4
5% NaHCO3
alc. KOH, NH₂OH-HCI, HCI, FeCl3
Brz with light
H₂O
Benzenesulfonyl chloride, NaOH, HCI
VISIBLE RESULT
Red orange solution
Colorless solution
Yellow-orange precipitate
No formation of layers
Purple solution
(5)
Yellow solution
No visible reaction
(8)
Solution solution
INFERENCE
(1)
Not an alkyne
(2)
(3)
(4)
Carboxylic acid group absent
(6)
(7)
Anhydride group absent.
(9)
Transcribed Image Text:Molecular Formula: C4H₂N2O4 TEST/REAGENT(S) Brz, dark [Ag(NH3)2]NO3 2,4-DNPH Test ZnCl₂, HCI Neutral KMnO4 5% NaHCO3 alc. KOH, NH₂OH-HCI, HCI, FeCl3 Brz with light H₂O Benzenesulfonyl chloride, NaOH, HCI VISIBLE RESULT Red orange solution Colorless solution Yellow-orange precipitate No formation of layers Purple solution (5) Yellow solution No visible reaction (8) Solution solution INFERENCE (1) Not an alkyne (2) (3) (4) Carboxylic acid group absent (6) (7) Anhydride group absent. (9)
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