Table 1.1Molecular formulaSO3CO2NO2HCNCN-CIF2*H2COBF3Lewis Structure:C=N:Total number of e2groups around thecentral atomNumber of lone pairsaround the central atom1Electron geometrylinearMolecular geometryLinearApproximate bond angles180°Polaritypoplar

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Chemistry

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Chapter9: Covalent Bonding: Orbitals

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Problem 87CP: Consider the following computer-generated model of caffeine: Complete a Lewis structure for caffeine...

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Fumaric acid, C4H4O4, occurs in the metabolism of glucose in the cells of plants and animals. It is used commercially in beverages. The structural formula of fumaric acid is Maleic acid is the cis isomer of fumaric add. Using valence bond theory, explain why these isomers are possible.
The molecular orbital diagram of NO shown in Figure 10.47 also applies to the following species. Write the molecular orbital electron configuration of each, indicating the bond order and the number of unpaired electrons. (a) CN (b) CO (c) BeB (d) BC+ Figure 10.47 Molecular orbital diagram for nitric oxide (NO). The molecular orbital diagram for NO predicts a bond order of 2.5 and predicts that the molecule is paramagnetic with one unpaired electron. These predictions are verified by experimental measurements.
Phosphoserine is a less-common amino acid. (a) Identify the hybridizations of atoms I through 5. (b) What are the approximate values of the bond angles A, B. C, and D? (c) What are the most polar bonds in the molecule?
For each of the following molecules, state the bond angle (or bond angles, as appropriate) that you would expect to see on the central atom based on the VSEPR model. Would you expect the actual bond angles to be greater or less than this? a OF2 b NCl3 c CF2CF2 d GeF4
Consider the following computer-generated model of caffeine: Complete a Lewis structure for caffeine in which all atoms have a formal charge of zero (as is typical with most organic compounds). How many C and N atoms are sp2 hybridized? How many C and N atoms are sp3 hybridized? sp hybridized? How many and bonds are there?
5)In which molecular geometry or geometry‘s can you find bond angle close to 109.5°? I) trigonal planar ii) tetrahedral iii) square pyramidal iv) linear V) trigonal bipyramidal
Butadiene, C4H6, is a planar molecule that has the followingcarbon–carbon bond lengths:(a) Predict the bond angles around each of the carbon atomsand sketch the molecule. (b) From left to right, whatis the hybridization of each carbon atom in butadiene?(c) The middle C¬C bond length in butadiene (1.48 Å) isa little shorter than the average C¬C single bond length(1.54 Å). Does this imply that the middle C¬C bond in butadieneis weaker or stronger than the average C¬C singlebond? (d) Based on your answer for part (c), discuss what additional aspects of bonding in butadiene might supportthe shorter middle C¬C bond.
There are three different dichloroethylenes (molecular for-mula C₂H₂Cl₂), which we can designate X, Y, and Z. CompoundX has no dipole moment, but compound Z does. Compounds Xand Z each combine with hydrogen to give the same product:C₂H₂Cl₂ (X or Z) +H₂→ClCH2-CH2Cl What are the structures of X, Y, and Z? Would you expect com-pound Y to have a dipole momen
1. ionization of Cl2 (Cl2 —> Cl2+ + e-) leads to a shortening of the Cl-Cl distance (199 pm in Cl2, 189 pm in Cl2+), why? 2. why the C-O bond distance is nearly identical in CO (113 pm) and CO+ (112 pm)? 3. Derive the MO diagram of a linear C-H (i.e. one carbon atom bonded to one hydrogen atom). Draw out the MOs for orbitals containing electrons Would you expect C-H to behave as a carbocation, carbanion, or radical? Would removal of one electron from C-H to generate C-H+ increase or decrease the bond length between carbon and hydrogen?
Draw orbital diagrams (boxes with arrows in them) to represent the electron configurations—without hybridization—for all the atoms in SF2. Circle the electrons involved in bonding. Draw a three-dimensional sketch of the molecule and show orbital overlap. What bond angle do you expect from the unhybridized orbitals? How well does valence bond theory agree with theexperimentally measured bond angle of 98.2°?
Which hybrid orbitals overlap in the C - O bond in CF₂O? A) Csp² - Os B) Csp² - Osp² C) Csp² - Osp³ D) Csp³ - Osp³ E) Csp³ - Osp
What atomic orbitals of carbon are used for the formation of the sigma bond component of the C-C double bond? A. 2sp2 atomic orbitals (Orbital atom 2sp2) B. 2p atomic orbitals (Orbital atom 2p) C. 2sp3 atomic orbitals (Orbital atom 2sp3) D. 2sp atomic orbitals (Orbital atom 2sp)

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Molecular formula Lewis Structure SO3 CO2 NO2 Total number ofe groups around the central atom Number of lone pairs around the central atom Electron geometry Molecular geometry Approximate bond angles Polarity