Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.3QAP
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Question
Kindly predict the solubility of the given structure below (first photo) by assigning the correct functional groups. Refer to the table for the values and examples are on the second photo. Please illustrate and solve the solubility and identify the conpound if it's water soluble or not.
Transcribed Image Text:N.
ÓH
Kindly predict the solubility of the given
structure.
IZ
N.
Transcribed Image Text:pi Value
Fragment
Cuide
C (aliphatic/cyclic)
+0.5
C (alkene-aliphatlc/cyclic)
+0.33
(phenyl/benzene ring) C,H,-
+2.0
>/= to +0.5
Halogens (CI, F, Br)
+0.5
water insoluble
O,NO
+0.2
Intramolecular hydrogen bonding (IMHB)
+0.65
< +0.5
+0.5
water soluble
(carboxylic acid) O=C-o
-0.7
(amlde) O=C-N
-0.7
O(hydroxyl, phenol, ether)
-1.0
Imine (included) = -1.O N (amine-aliphatic/cyclic/aromatic)
-1.0
O,N (aliphatic)
-0.85
O,N (aromatic)
-0.28
Benzene 2
TOTAL: 3.95
WATER INSOLUBLE
Caliphatic 0 5
N cyclic= -1
N-
O=CN = -0.7
N-
Benzene 2
IMHB=0.65
C-aliphatic=0 5
Total: 5.28
Carbon
aliphatic=
0.5
WATER INSOLUBLE
H,CO
Carbon
aliphatic%=
05
Сyclic
alkene=0.33
H,CO
Carbon
alphatic=
0,5
OCH3
Carbon
OCH, aliphatic=
05
H.
Carbon
cyclic3 05
H,C
Benzene=2
Carbon
aliphatice
0.5
IMHB= 0 65
I ZI
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