NH2 H3C CH, но H,N., A NH2 6 M H,SO, H3C. H,C H3C. H,C HO, H,C CH, CH CH NaOAc 2,3-dimethyl-2,3-butanediol (1) (pinacol) 3,3-dimethyl-2-butanone (2) (pinacolone) 3,3-dimethyl-2-butanone semicarbazone (3) m. р. - 157 °C d (g/mL) or M Rxn Weight or (mmol/mL) Compound MW, g/mol mmol Equivalents V (g or mL) Pinacol (1) 118.18 6.739 56.9 1.00 3.16 0.088 6M H;SO. 98.08 30 mL 180 Pinacolone (2) 100.16 0.50 g semicarbazide HCI 111.53 0.50 g 0.078 1.00 g/mL 3 mol/L 4.48 9.75 NaOAc 82.03 0.80 g 2.0

World of Chemistry, 3rd edition
3rd Edition
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Chapter20: Organic Chemistry
Section: Chapter Questions
Problem 2STP
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3.

 

H3C CH3
но
H2N,
N.
NH2
6 M H2SO,
NH2
H3C.
CH3
H3C
CH3
H3C.
H3C
HO.
CH3
ČH3
H3C CH3
2,3-dimethyl-2,3-butanediol (1)
(pinacol)
3,3-dimethyl-2-butanone (2)
(pinacolone)
3,3-dimethyl-2-butanone
semicarbazone (3)
m. p. = 157 °C
d (g/mL) or M Rxn Weight or
Compound
MW, g/mol
mmol
Equivalents
(mmol/mL)
V (g or mL)
Pinacol (1)
118.18
6.739
56.9
1.00
3.16
0. 088
6M H;SO.
98.08
30 mL
180
Pinacolone (2)
100.16
0.50 g
semicarbazide
HCI
0.50 g
0.078
111.53
1.00 g/mL
3 mol/L
448
975
NaOAc
82.03
0.80 g
2.0
Transcribed Image Text:H3C CH3 но H2N, N. NH2 6 M H2SO, NH2 H3C. CH3 H3C CH3 H3C. H3C HO. CH3 ČH3 H3C CH3 2,3-dimethyl-2,3-butanediol (1) (pinacol) 3,3-dimethyl-2-butanone (2) (pinacolone) 3,3-dimethyl-2-butanone semicarbazone (3) m. p. = 157 °C d (g/mL) or M Rxn Weight or Compound MW, g/mol mmol Equivalents (mmol/mL) V (g or mL) Pinacol (1) 118.18 6.739 56.9 1.00 3.16 0. 088 6M H;SO. 98.08 30 mL 180 Pinacolone (2) 100.16 0.50 g semicarbazide HCI 0.50 g 0.078 111.53 1.00 g/mL 3 mol/L 448 975 NaOAc 82.03 0.80 g 2.0
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