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![Which one of the following compounds will have the lowest wavenumber for the carbonyl absorption?
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O III
O IV
OV
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IV
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- For the following reaction, choose a statement that best describes differences in the FTIR spectra of the starting reagent and product. :0 1) CH3MgBr 2) H3O+ ? O The absorbance at 3500-3200 cm-1 will decrease and a new absorbance at 1730 cm-1 will increase. O The absorbances at 1730 cm-1 and 3500-3200 cm-1 will decrease. O The absorbances at 1730 cm-1 and 3500-3200 cm-1 will increase. O The absorbance at 1730 cm-1 will decrease and a new absorbance at 3500-3200 cm-1 will increase.How many non-equivalent proton signals are expected in chloroethene (shown)? CI H H HWhich molecule would have a large M-18 peak in its mass spectrum? OV O III Oll ON OH || ||| IV Br V -NH₂
- 2. Both the compounds shown below contain a carbonyl group but there is slight variation in the wavenumber of the peak as shown below. h f 1720 cm-1 1680 cm-1 Explain the possible reason of this variation.When the 1HNMR spectrum of an alcohol is run in dimethylsulfoxide (DMSO) solvent rather than in chloroform, exchange of the Ο-H proton is slow and spin-spin splitting is seen between the Ο-H proton and C-H protons on the adjacent carbon. What spin multiplicities would you expect for the hydroxyl protons in the following alcohols? (a) 2-Methyl-2-propanol (b) Cyclohexanol (c) Ethanol (d) 2-Propanol (e) Cholesterol (f) 1-Methylcyclohexanol8). For the following molecule: I I II Which double bond indicated should give the STRONGEST absorption signal? 9). Which one of the following compounds will have the lowest wavenumber for carbonyl absorption? II III III NH2 IV V
- Choose the data that best matches this partial structure; the hydrogens represented by the data are in bold: H H H Od, 2H, 4.0 ppm Os, 2H, 7.1 ppm Od, 2H, 6.8 ppm Ot, 2H, 6.9 ppm HSelect the correct structure corresponding to the 'H NMR spectrum below. Integration values are shown above/adjacent to each signal. C4H¬OC1 1.50 1.00 1.01 II A) CH;CCHCH3 II В) CICH-CCH-CH, ČI C) CH;CH2CH2CI D) CH;CCH,CH,CI ОА В CWhich of the following wavenumber corresponds to the fingerprint region on an IR spectrum? 1500-4000 cm 400-4000 cm-1 O 400-1500 cm-1 O 1600-1850 cm cm-1 Tamibian
- Which molecule below has absorption bands in its infrared (IR) spectrum at 2720 cm-1 and 2820 cm-1? OH OH compound A compound B compound C compound D compound E Please click here if image does not display. O compound A O compound C O compound E compound B O compound DQ3. The following spectra belongs to either benzoic anhydride, aniline and phenol. Identify and describe the important absorption in the spectral data shown below. 4000 3440 1979 1 217 3310 9 1000 19 1979 1 3460 44 2906 06 3396 58 2630 84 320984 1918 1 30954 72 OL FLOE 1340 06 1325 79 1300 79 1276 20 103900 182605 1174 47 106904 1028 72 10 966 616 64 640 1 86 929 3041 32 1500 4 115499 2013 00 1400 60 1117 79 C0031 a PIR 1000 Wild PUBERGH 1500 1000 100 WheDetermine the multiplicity of the signal (pointed with single headed arrow) in the expected ¹H NMR spectrum of the following compound. ? N H N CH3 Nicotine
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