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- Differentiate between Uni-molecular and Bi-molecular?(a) How does the structure of diborane (B2H6) differ fromthat of ethane (C2H6)? (b) Explain why diborane adoptsthe geometry that it does. (c) What is the significance ofthe statement that the hydrogen atoms in diborane aredescribed as “hydridic”?Consider following reaction: HgO (s) -> Hg(l) + ½ O2 (g) Delta H = +90.7 kj/mol. What quantity of heat in kj/mol is required to produce one mole HgO? Write your answer without units. Given the following data 2ClF(g) + O2(g) --> Cl2O(g) + F2O (g) Delta H= 167.4 kJ I 2ClF3(g) + 2O2(g) --> Cl2O(g) + 3F2 O (g) Delta H= 341.4 kJ II 2 F2(g) + O2(g) ---> 2F2O (g) Delta H= -43.4 kJ III Calculate the delta H in kJ for below reaction: ClF(g) + F2(g) ---> ClF3(g)
- part: 6a: g,h,i(a) Compare the bond enthalpies (Table 8.3) of the carbon–carbon single, double, and triple bonds to deduce an averageπ -bond contribution to the enthalpy. What fraction ofa single bond does this quantity represent? (b) Make a similarcomparison of nitrogen–nitrogen bonds. What do youobserve? (c) Write Lewis structures of N2H4, N2H2, and N2,and determine the hybridization around nitrogen in eachcase. (d) Propose a reason for the large difference in yourobservations of parts (a) and (b).Rank each of the representations of NOCl from best to worst, placing the best structure on top and the worst at the bottom.
