One mole of acetyl chloride is added to a liter of triethylamine, resulting in a vigorous exothermic reaction. Once thereaction mixture has cooled, 1 mole of ethanol is added. Another vigorous exothermic reaction results. The mixture isanalyzed and found to contain triethylamine, ethyl acetate, and triethylammonium chloride. Propose mechanisms for thetwo exothermic reactions.

One mole of acetyl chloride is added to a liter of triethylamine, resulting in a vigorous exothermic reaction. Once thereaction mixture has cooled, 1 mole of ethanol is added. Another vigorous exothermic reaction results. The mixture isanalyzed and found to contain triethylamine, ethyl acetate, and triethylammonium chloride. Propose mechanisms for thetwo exothermic reactions.

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter19: Enolate Anions And Enamines

Section: Chapter Questions

Problem 19.40P: Enamines normally react with methyl iodide to give two products: one arising from alkylation at...

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