Organic compounds that contain large proportions of nitrogen and oxygen tend to be unstable and are easily decomposed. Hexanitroethane, C2(NO2)6, decomposes according to the equation C2(NO2)6– 2NO, + 4NO + 2CO; The reaction in CCI4 solvent is first order with respect to C2(NO2)6. At 63.7 °C, k = 0.000254 s'* and at 112.6°C, k = 0.0126s'!. (a) What is the half-life of C{NO2), at 63.7 °C? 1 seconds eTextbook and Media (b) What is the half-life of C2(NO2), at 112.6 °C? seconds (c) If0.100 mol of C2(NO2)6 is dissolved in CCI4 at 63.7°C to give 1.00 L of solution, what will be the C2(NO2)6 concentration after 50.0 minutes? A M

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.36PAE: The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a role in the formation of nitrogen dioxide in...
icon
Related questions
Question
Organic compounds that contain large proportions of nitrogen and oxygen tend to be unstable and are easily decomposed.
Hexanitroethane, C2(NO2)6, decomposes according to the equation
C2(NO2)6- 2NO, + 4NO + 2CO,
The reaction in CCl, solvent is first order with respect to Cz{NO2)s At 63.7°C, k= 0.000254 s* and at 112.6°C, k = 0.0126s*.
(a)
What is the half-life of C2{NO2); at 63.7 °C? i
seconds
e Textbook and Media
(b)
What is the half-life of C2(NO2)s at 112.6 °C?
seconds
(c)
IF0.100 mol of C2(NO2)6 is dissolved in CCI4 at 63.7°C to give 1.00 L of solution, what will be the C2(NO2), concentration after
50.0 minutes? i
M
(d)
What is the value of the activation energy of this reaction, expressed in kilojoules? i
kJ/mol
(e)
What is the rate constant at 159.4 °C?
Transcribed Image Text:Organic compounds that contain large proportions of nitrogen and oxygen tend to be unstable and are easily decomposed. Hexanitroethane, C2(NO2)6, decomposes according to the equation C2(NO2)6- 2NO, + 4NO + 2CO, The reaction in CCl, solvent is first order with respect to Cz{NO2)s At 63.7°C, k= 0.000254 s* and at 112.6°C, k = 0.0126s*. (a) What is the half-life of C2{NO2); at 63.7 °C? i seconds e Textbook and Media (b) What is the half-life of C2(NO2)s at 112.6 °C? seconds (c) IF0.100 mol of C2(NO2)6 is dissolved in CCI4 at 63.7°C to give 1.00 L of solution, what will be the C2(NO2), concentration after 50.0 minutes? i M (d) What is the value of the activation energy of this reaction, expressed in kilojoules? i kJ/mol (e) What is the rate constant at 159.4 °C?
Expert Solution
steps

Step by step

Solved in 4 steps with 4 images

Blurred answer
Knowledge Booster
Chemical Equilibrium
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry for Engineering Students
Chemistry for Engineering Students
Chemistry
ISBN:
9781337398909
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781133949640
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:
9781285869759
Author:
Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:
Cengage Learning