ozonation and the precipitation of Lf(OH)3 (s) via the following reactions: реб Eho, O3 (g) + 2H* + 2e- +→ 02 (9) + H2O 35.06 2074 Lf(OH)3(s) + 2H* + e- +→ Lf2+ + 3H20 33.87 2005 (a) Write the balanced overall reaction. (b) Calculate the equilibrium constant for the reaction.

General Chemistry - Standalone book (MindTap Course List)
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Chapter21: Chemistry Of The Main-group Elements
Section: Chapter Questions
Problem 21.190QP
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We are designing a new system to disinfect and remove Lf from water in a single step via
ozonation and the precipitation of Lf(OH)3 (s) via the following reactions:
peo
Eho,
mv
O3 (g) + 2H* + 2e- +→ 02 (9) + H20
35.06
2074
Lf(OH)3(s) + 2H* + e +→ Lf2+ + 3H20
33.87
2005
(a) Write the balanced overall reaction.
(b) Calculate the equilibrium constant for the reaction.
(c) Ignoring the presence of any complexes, what is the required concentration of O3(g)
to decrease the Lf concentration to below 1nM, assuming the pH remains constant at
pH = 8 and the dissolved oxygen concentration (DO) is equal to 10 mg/L (Henry's
constant for O2 is 769 atm/(mol/L) = 31.4 M/M.
Transcribed Image Text:We are designing a new system to disinfect and remove Lf from water in a single step via ozonation and the precipitation of Lf(OH)3 (s) via the following reactions: peo Eho, mv O3 (g) + 2H* + 2e- +→ 02 (9) + H20 35.06 2074 Lf(OH)3(s) + 2H* + e +→ Lf2+ + 3H20 33.87 2005 (a) Write the balanced overall reaction. (b) Calculate the equilibrium constant for the reaction. (c) Ignoring the presence of any complexes, what is the required concentration of O3(g) to decrease the Lf concentration to below 1nM, assuming the pH remains constant at pH = 8 and the dissolved oxygen concentration (DO) is equal to 10 mg/L (Henry's constant for O2 is 769 atm/(mol/L) = 31.4 M/M.
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