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- Lithocholic acid is an A–B cis steroid found in human bile. Draw lithocholic acid showing chair conformations, as in Figure 27-11, and tell whether the hydroxyl group at C3 is axial or equatorial.Most naturally occurring amino acids have chiral centers (the asymmetric a carbon atoms)that are named (S) by the Cahn–Ingold–Prelog convention (Section 5-3). The commonnaturally occurring form of cysteine has a chiral center that is named (R), however.(a) What is the relationship between (R)-cysteine and (S)-alanine? Do they have the oppositethree-dimensional configuration (as the names might suggest) or the same configuration?(b) (S)-Alanine is an l-amino acid (Figure 24-2). Is (R)-cysteine a d-amino acid or anl-amino acid?Construct a model of methane (CH4) using MolView and answer the following: Can it be superimposed on its mirror image? (Y/N) Does methane contain a plane of symmetry? (Y/N) Is methane chiral? (Y/N)
- Fill in the blank completely including stereochemistry if necessary.Draw the meso form of (1R,4R)-cycloheptane-1,4-diol Use the wedge/hash bond tools to indicate stereochemistry where it exists. Show stereochemistry in a meso compound.Which has the greater polarizability? Explain.(a) Br- or I- (b) CH2 = CH2 or CH3—CH3 (c) H2O or H2Se