P1) What is the correct IUPAC name of the compound below? Br OH otions is Fischer A) 3-(2-bromopropyl)-6,6-dimethylheptan-2-ol B) 5-bromo-3-(3,3-dimethylbutyl)hexan-2-ol C) 5-(2-bromopropyl)-2,2-dimethylheptan-6-ol D) 7-bromo-5-(1-hydroxyethyl)-2,2-dimethyloctane 22) What would be the alcohol product if MeMgBr/ether & H3O* are ac

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter21: Benzene And The Concept Of Aromaticity
Section: Chapter Questions
Problem 21.25P: Compound H (C8H6O3) gives a precipitate when treated with hydroxylamine in aqueous ethanol and a...
icon
Related questions
icon
Concept explainers
Question
18 and 21
21) What is the correct IUPAC name of the compound below?
Br
OH
ctions is Fische
A) 3-(2-bromopropyl)-6,6-dimethylheptan-2-ol
B) 5-bromo-3-(3,3-dimethylbutyl)hexan-2-ol
C) 5-(2-bromopropyl)-2,2-dimethylheptan-6-ol
D) 7-bromo-5-(1-hydroxyethyl)-2,2-dimethyloctane
22) What would be the alcohol product if MeMgBr/ether & H;O* are added to 3
3
(1) p-ethyl benzoic acid, (ii) p-nitro benzoic acid, (iii) p-cyano benzoit at
(iii)
30) Show an increase in the oruUI
(c) (i) < (ii) < (iii) (d) (ii
Transcribed Image Text:21) What is the correct IUPAC name of the compound below? Br OH ctions is Fische A) 3-(2-bromopropyl)-6,6-dimethylheptan-2-ol B) 5-bromo-3-(3,3-dimethylbutyl)hexan-2-ol C) 5-(2-bromopropyl)-2,2-dimethylheptan-6-ol D) 7-bromo-5-(1-hydroxyethyl)-2,2-dimethyloctane 22) What would be the alcohol product if MeMgBr/ether & H;O* are added to 3 3 (1) p-ethyl benzoic acid, (ii) p-nitro benzoic acid, (iii) p-cyano benzoit at (iii) 30) Show an increase in the oruUI (c) (i) < (ii) < (iii) (d) (ii
D) 8
E) 5
18) Deduce the identity of the following compound from the 1H NMR data given.
C3H100: ô 3.4 (3H, singlet), 4.5 (2H, singlet), 7.2 (5H, apparent singlet) (ppm)
(а) Ph-CH-CH2ОН
(b) Ph-CH2-O-CH3
(c) p-CH3-Ph-O-CH3
(d) p-CH3CH2-Ph-OH
19)
Deduce the identity of the following compound from the 13C NMR data given.
C9H12: 8 21.3 (quartet), 127.2 (doublet), 138.0 (singlet) (ppm)
(a) 1,3,5-trimethyl benzene
(d) 1-ethyl-3-methyl benzene
(b) 1-ethyl-4-methyl benzene
(c) 1,2,4-trimethyl benzene
20) Which of the following reagents would be suitable for making "ethyl-benzene" from
"acetophenone" (i.e. via a reduction process)?
(a) Zn/HCl
(b) NHNH>/KOН
(c) LAH/H;O* (d) NABH4/MEOH
21) What is the correct IUPAC name of the compound below?
Br
Transcribed Image Text:D) 8 E) 5 18) Deduce the identity of the following compound from the 1H NMR data given. C3H100: ô 3.4 (3H, singlet), 4.5 (2H, singlet), 7.2 (5H, apparent singlet) (ppm) (а) Ph-CH-CH2ОН (b) Ph-CH2-O-CH3 (c) p-CH3-Ph-O-CH3 (d) p-CH3CH2-Ph-OH 19) Deduce the identity of the following compound from the 13C NMR data given. C9H12: 8 21.3 (quartet), 127.2 (doublet), 138.0 (singlet) (ppm) (a) 1,3,5-trimethyl benzene (d) 1-ethyl-3-methyl benzene (b) 1-ethyl-4-methyl benzene (c) 1,2,4-trimethyl benzene 20) Which of the following reagents would be suitable for making "ethyl-benzene" from "acetophenone" (i.e. via a reduction process)? (a) Zn/HCl (b) NHNH>/KOН (c) LAH/H;O* (d) NABH4/MEOH 21) What is the correct IUPAC name of the compound below? Br
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 2 steps with 2 images

Blurred answer
Knowledge Booster
Nomenclature of Organic Compounds
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9781305580350
Author:
William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9781305080485
Author:
John E. McMurry
Publisher:
Cengage Learning