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panone (acetone) The structure of the alkene D CH CIHCH CHCIL CH: O (CH)C-C(CHH): O (CH:)CCH=CH O CH:CH;CH=C(CH; The condensation of 6-aminohexanoic acid, u he used to prepare a

panone (acetone) The structure of the alkene D CH CIHCH CHCIL CH: O (CH)C-C(CHH): O (CH:)CCH=CH O CH:CH;CH=C(CH; The condensation of 6-aminohexanoic acid, u he used to prepare a

Organic Chemistry
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter11: Ethers, Epoxides, And Sulfides
Section: Chapter Questions
Problem 11.37P: Following are the steps in the industrial synthesis of glycerin. Provide structures for all...
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Answer Q47, 48

propanone (acetone) The structure of the alkene (A) sp" 38 The reaction between bromine and ethene is an example of (A) (B) (B) sp' (C) sp (D) s'p SPA (A) CH CCH CHCILCH: (B.) (CH:)CCH CHy Free-radical addition (CH).C-C(CIH): (C.) CH CH:CH-C(CH;): Electrophilic substitution (D.) 44 The condensation of 6-aminohexanoie acid, HN(CH:).COO1, can be used to prepare a common type of ny lon. Which of the following represents the repeated unit of the polymer? (- NH(CH,),CO(CH,), -In (C) Electrophilic addition (D) 39 The compound CH3-CH=CH-CH(OH)CH, Nucleophilic addition can show (A.) (A) (B) Optical isomerism only Geometric and optical isomerism |- NH(CH,),C00 - n (B.) (C) |- NH(CH,), CO -ln Geometric, optical, and functional group (C) Isomerism (D) 40 Which reagent couid be uscd preparation of the following compound in the presence of mineral acid as a catalvst |- NH, (CH,),CO - (D.) 45 Wliat is the expected structure of alanine. Positional isomerism COOH in a neutral nmedium H. CH,-CH,-CH,-C H,N--COOH H N- C- COOH CH3 (A) (B) (C) O CHs CHCHLCHOH and CHCOOH CHOH and CH.CH CH CH,OH C1-OH and CH CH CH COOH CH CHCIH-CHOH and ClHCOCI CH3 13 (D) Questions 41-12 tor the reaction H. H3N-C-CO0 H,N-C-COO NO. CH3 alkaline CH3 D 41 Give the Nr re olY 46 Identily the compound which will react with 2-naphthot to give an azodyeat a temperature NO: NO. NO below 10°C HOOC NH-NH CH; COOH (H,C),-NH D. 42The structure of compound X is NO, NO, -NO, NO N NCI CN CH CH 43 An alkene, C.H12 was treated with ozone (O) 47 What could be the organic produci of the - following reactions? and then water was added. The only product was 13
Transcribed Image Text:propanone (acetone) The structure of the alkene (A) sp" 38 The reaction between bromine and ethene is an example of (A) (B) (B) sp' (C) sp (D) s'p SPA (A) CH CCH CHCILCH: (B.) (CH:)CCH CHy Free-radical addition (CH).C-C(CIH): (C.) CH CH:CH-C(CH;): Electrophilic substitution (D.) 44 The condensation of 6-aminohexanoie acid, HN(CH:).COO1, can be used to prepare a common type of ny lon. Which of the following represents the repeated unit of the polymer? (- NH(CH,),CO(CH,), -In (C) Electrophilic addition (D) 39 The compound CH3-CH=CH-CH(OH)CH, Nucleophilic addition can show (A.) (A) (B) Optical isomerism only Geometric and optical isomerism |- NH(CH,),C00 - n (B.) (C) |- NH(CH,), CO -ln Geometric, optical, and functional group (C) Isomerism (D) 40 Which reagent couid be uscd preparation of the following compound in the presence of mineral acid as a catalvst |- NH, (CH,),CO - (D.) 45 Wliat is the expected structure of alanine. Positional isomerism COOH in a neutral nmedium H. CH,-CH,-CH,-C H,N--COOH H N- C- COOH CH3 (A) (B) (C) O CHs CHCHLCHOH and CHCOOH CHOH and CH.CH CH CH,OH C1-OH and CH CH CH COOH CH CHCIH-CHOH and ClHCOCI CH3 13 (D) Questions 41-12 tor the reaction H. H3N-C-CO0 H,N-C-COO NO. CH3 alkaline CH3 D 41 Give the Nr re olY 46 Identily the compound which will react with 2-naphthot to give an azodyeat a temperature NO: NO. NO below 10°C HOOC NH-NH CH; COOH (H,C),-NH D. 42The structure of compound X is NO, NO, -NO, NO N NCI CN CH CH 43 An alkene, C.H12 was treated with ozone (O) 47 What could be the organic produci of the - following reactions? and then water was added. The only product was 13
48 Select the strongest acid from the following: FCH,CO;H: CICH CO-H: BRCH CO:H ICH,CO,l is FCH CO:H CICH;CO.H BRCH2CO;H ICH,CO,H Br/NAOH CH,CONH, Heat (A) (B) (A.) (В) (C.) (D.) CH:COBr CH,CH2NH, CH CONHBr CHINII: (C) (D) DIRECTIONS. Each of the following questions consists of a statement in the left-hand column followed by a second statement in the right land column Decide whether the first statement is true or false Decide whether the second statement is true or false Then on the answer sheet mark: If both statements are true and the second statement is the correct explanation of the first statement If both statemments are true but the second statement is NOT a correct explanation of the first B. statement If the first stateinent is true and the second statement is false If the first statement is false but the second statement is true DIRECTIONS SUMMARY First Statement Second Statement Second statement is a correct explanation of the first Second statement is NOT a corect explanation of the first True True True True True False D False True First statement Second statement P'henylethanone (acetophenone) gives a phenylethanone (pheny lacetone) contain the -COCH group Aniline (pheny lamine) reacts with ice- Phenylamine (Aniine) is a primary aromatic 49. positive iodoform test 50. cold nitrous acii liherating nitrogen gas and amine forming phenol SET 3: MCQ (CGCEB 2011). moles of water Which of the following elements is most likely to have the following ionisation energies (kJmol")? 780, 1580, 3230, 4360, 16000 (A] Aluminium (B] Silicon [C] Magnesium (D] Phosphorus Question experiment. Ah vitr : place in a test tube and 5 cm (0.05 mole) of hydrochloric acid was added. On shaking the test tube, the solid dissolved. On adding 2 cm' of 1. How of 3. many crystallization are there in 0.2 mole of sodium sulphate Na, SO,. 10H,0? (A) 0.2 (B) 2 (C) S (D) 20 2. In which of the following equations does the oxidation state (number) of the determined Hom undereo the greatest change 4-7 concern the following (A) (B) Ba0 + So, Baso, Cl, + 2MN0, - 2MN0, + 201 (C) (D) 2FECI, + SnCl, 2FECI, + SnCl, 14
Transcribed Image Text:48 Select the strongest acid from the following: FCH,CO;H: CICH CO-H: BRCH CO:H ICH,CO,l is FCH CO:H CICH;CO.H BRCH2CO;H ICH,CO,H Br/NAOH CH,CONH, Heat (A) (B) (A.) (В) (C.) (D.) CH:COBr CH,CH2NH, CH CONHBr CHINII: (C) (D) DIRECTIONS. Each of the following questions consists of a statement in the left-hand column followed by a second statement in the right land column Decide whether the first statement is true or false Decide whether the second statement is true or false Then on the answer sheet mark: If both statements are true and the second statement is the correct explanation of the first statement If both statemments are true but the second statement is NOT a correct explanation of the first B. statement If the first stateinent is true and the second statement is false If the first statement is false but the second statement is true DIRECTIONS SUMMARY First Statement Second Statement Second statement is a correct explanation of the first Second statement is NOT a corect explanation of the first True True True True True False D False True First statement Second statement P'henylethanone (acetophenone) gives a phenylethanone (pheny lacetone) contain the -COCH group Aniline (pheny lamine) reacts with ice- Phenylamine (Aniine) is a primary aromatic 49. positive iodoform test 50. cold nitrous acii liherating nitrogen gas and amine forming phenol SET 3: MCQ (CGCEB 2011). moles of water Which of the following elements is most likely to have the following ionisation energies (kJmol")? 780, 1580, 3230, 4360, 16000 (A] Aluminium (B] Silicon [C] Magnesium (D] Phosphorus Question experiment. Ah vitr : place in a test tube and 5 cm (0.05 mole) of hydrochloric acid was added. On shaking the test tube, the solid dissolved. On adding 2 cm' of 1. How of 3. many crystallization are there in 0.2 mole of sodium sulphate Na, SO,. 10H,0? (A) 0.2 (B) 2 (C) S (D) 20 2. In which of the following equations does the oxidation state (number) of the determined Hom undereo the greatest change 4-7 concern the following (A) (B) Ba0 + So, Baso, Cl, + 2MN0, - 2MN0, + 201 (C) (D) 2FECI, + SnCl, 2FECI, + SnCl, 14
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