Part 1: Preparation of the Grignard reagent: Br MgBr B view structure view structure Draw the intermediate product formed above and select the correct reagent A. MgBr2 O PBR3 O Br2 O CH3B Draw the intermediate product formed above and select the correct reagent B. Mgl, MgBr2 Mg O MgO Part 2 out of 2 Grignard reaction: „MgBr [1] C HO. (2) H20 Draw the reagent C. draw structure .

Part 1: Preparation of the Grignard reagent: Br MgBr B view structure view structure Draw the intermediate product formed above and select the correct reagent A. MgBr2 O PBR3 O Br2 O CH3B Draw the intermediate product formed above and select the correct reagent B. Mgl, MgBr2 Mg O MgO Part 2 out of 2 Grignard reaction: „MgBr [1] C HO. (2) H20 Draw the reagent C. draw structure .

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions

Section: Chapter Questions

Problem 20.56P: Write the products of the following sequences of reactions. Refer to your reaction roadmaps to see...

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We now continue the introduction of organic chemistry reaction roadmaps. Because of the many new functional groups that will be introduced in coming chapters, we recommend that you make a new roadmap to accommodate the reactions in Chapters 1518. To make your own reaction roadmap for Chapters 1518, take a blank sheet of paper and write the following functional groups in the orientations shown. Fill the entire sheet of paper and leave plenty of room between functional groups. Most students find it helpful to use a poster-sized piece of paper filled out in landscape orientation. Refer to the Study Guide section of this chapter. Draw arrows between functional groups to account for each reaction. Write the reagents required to bring about each reaction next to the arrow. Then record any regiochemistry or stereochemistry considerations relevant to the reaction. You should also record any key aspects of the mechanism, such as formation of a carbocation intermediate, as a helpful reminder. It is important to keep track of all reactions that make carbon-carbon bonds, because these will help you build large molecules from smaller fragments. On the above organic chemistry reaction roadmap template, the information for the Simmons-Smith reaction, the seventh reaction in the Study Guide section has been added to help you get started. For this reaction roadmap, do not write an arrow for reactions 1, 2, and 4 explicitly, because these are considered reagents, which are prepared immediately prior to use. A reaction roadmap is used to indicate interconversion of molecules with more stable functional groups. Appendix 10 contains a series of roadmaps for different sections of the book, but you should use those for reference only after you have completed your own.
Write the products of the following sequences of reactions. Refer to your reaction roadmaps to see how the combined reactions allow you to navigate between the different functional groups. Note that you will need your old Chapters 611, Chapters 1518, and Chapter 19 roadmaps along with your new Chapter 20 reaction roadmap for these.