PERTINENT CALCULATIONS Remember: rate = k[C25H30CIN3]"[OH¯]° where n = 0 since excess OH was used. %3D 1. Refer to your graphs and complete table below. Linear correlation (r – value) Graph Kinetic Run I Kinetic Run II Average r - value absorbance vs time In (absorbance) vs time (absorbance) vs time 2. Based on the average linear correlation (r2 -value) the reaction order, m, with respect to crystal violet, CV, is Explain 3. Write the rate law 4 The slope, and therefore pseudo" rate constant, ki', is at T1. OC and ko' is at T2

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter15: Molecular Luminescence Spectrometry
Section: Chapter Questions
Problem 15.15QAP: The following lifetimes were measured for the chloride quenching of quinine sulfate given in Example...
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PERTINENT CALCULATIONS
Remember:
rate = k[C25H30CIN3]"[OH_]º where n = 0 since excess OH was used.
%3D
1. Refer to your graphs and complete table below
Linear correlation (r – value)
Graph
Kinetic Run I
Kinetic Run II Average r- value
absorbance vs time
In (absorbance) vs time
/(absorbance) vs time
2. Based on the average linear correlation (r2 -value) the reaction order, m, with respect to crystal
violet, CV, is
Explain
3. Write the rate law:
4 The slope, and therefore "pseudo" rate constant, ki', is
at T1.
°C and ko' is
at T2
Transcribed Image Text:PERTINENT CALCULATIONS Remember: rate = k[C25H30CIN3]"[OH_]º where n = 0 since excess OH was used. %3D 1. Refer to your graphs and complete table below Linear correlation (r – value) Graph Kinetic Run I Kinetic Run II Average r- value absorbance vs time In (absorbance) vs time /(absorbance) vs time 2. Based on the average linear correlation (r2 -value) the reaction order, m, with respect to crystal violet, CV, is Explain 3. Write the rate law: 4 The slope, and therefore "pseudo" rate constant, ki', is at T1. °C and ko' is at T2
PERTINENT CALCULATIONS
Remember:
rate = k[C25H30CIN3]"[OH_]" where n =0 since excess OH was used.
n3=
1. Refer to your graphs and complete table below
Linear correlation (r- value)
Graph
Kinetic Run I
Kinetic Run II Average r- value
absorbance vs time
0.9972
0.9955
0.9964
In (absorbance) vs time
0.9978
0.9994
0.9986
2/(absorbance) vs time
0.9805
0.9879
0.9952
2. Based on the average linear correlation (r2 -value) the reaction order, m, with respect to crystal
violet, CV, is
Explain.
3. Write the rate law.
4.
The slope, and therefore pseudo" rate constant, kr', is
at T1.
CC, and ko' is
at T2
Transcribed Image Text:PERTINENT CALCULATIONS Remember: rate = k[C25H30CIN3]"[OH_]" where n =0 since excess OH was used. n3= 1. Refer to your graphs and complete table below Linear correlation (r- value) Graph Kinetic Run I Kinetic Run II Average r- value absorbance vs time 0.9972 0.9955 0.9964 In (absorbance) vs time 0.9978 0.9994 0.9986 2/(absorbance) vs time 0.9805 0.9879 0.9952 2. Based on the average linear correlation (r2 -value) the reaction order, m, with respect to crystal violet, CV, is Explain. 3. Write the rate law. 4. The slope, and therefore pseudo" rate constant, kr', is at T1. CC, and ko' is at T2
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ISBN:
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