ple Cholce Gi Saved Select the corTrect stepwise mechanism for the reaction shown below, which results in ring expansion of a six-membered ring to a seven-membered ring. Solution OH Guided Solution H,0 H SO4 H,O CH, CH, 1.2-shift H,SO Hö -'OSH+ CH, OH CH CH, :0 H CH, HSO, + H,SO, CH, CH, CH H,O H,SO, 12-shift *H,O HSÖ, CH, OH CH, CH, 0 CH, HSO, +H,SO,

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter14: Elimination
Section: Chapter Questions
Problem 22E
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Question
e Choice i
Saved
CH,
CH,
CH,
H,0
1,2-shift
H,SO,
H-OSO,H
+ HSO,
Hö
H.
CH, OH
CH, 0H
HSO,
+ H,SO,
器 C
CH,
CH,
CH,
CH,
H,O
1,2-shift
H,SO,
H-OSO,H
HSÖ,
+ H,O
H.
CH, OH
CH,
CH, 0 H-
CH, HSO,
+ H,SO,
Transcribed Image Text:e Choice i Saved CH, CH, CH, H,0 1,2-shift H,SO, H-OSO,H + HSO, Hö H. CH, OH CH, 0H HSO, + H,SO, 器 C CH, CH, CH, CH, H,O 1,2-shift H,SO, H-OSO,H HSÖ, + H,O H. CH, OH CH, CH, 0 H- CH, HSO, + H,SO,
ultiple Cholce O
Saved
Select the correct stepwise mechanism for the reaction shown below, which results in ring expansion of
a six-membered ring to a seven-membered ring.
Solution
Guided Solution
OH
H20
*os H
CH,
CH,
CH,
1,2-shift
H,O
H,SO,
+HSO,
H-OSO,H
H.
CH, OH
CH,
CH, 0 H-
CH,
HSO,
+ H,SO,
CH
CH
CH,
CH,
1,2-shift
H,O
H,SO,
+H,0
HSÖ,
H.
CH, OH
CH,
CH, 0 H-
CH, HSO,
+ H,SO,
Transcribed Image Text:ultiple Cholce O Saved Select the correct stepwise mechanism for the reaction shown below, which results in ring expansion of a six-membered ring to a seven-membered ring. Solution Guided Solution OH H20 *os H CH, CH, CH, 1,2-shift H,O H,SO, +HSO, H-OSO,H H. CH, OH CH, CH, 0 H- CH, HSO, + H,SO, CH CH CH, CH, 1,2-shift H,O H,SO, +H,0 HSÖ, H. CH, OH CH, CH, 0 H- CH, HSO, + H,SO,
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