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- Explain how and why rearrangements occurduring Friedel-Crafts alkylation reactions formingmore than 1 product. Also illustrate therearrangement reaction from the aboveexample.Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides. One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(CzHs)3). 3SnCl4 + 4Al(C2H5)3 → 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.160 L of SnCl4 (d= 2.226 g/mL) was treated with 0.346 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). What is the theoretical yield in this experiment (mass of tetraethylstannane, Sn(C2H5)4)? If 0.257L of tetraethylstannane (d= 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?The reaction of an organic acid with an alcohol, inorganic solvent, to produce an ester and water is commonlydone in the pharmaceutical industry. This reactionis catalyzed by strong acid (usually H2SO4). A simpleexample is the reaction of acetic acid with ethyl alcoholto produce ethyl acetate and water: CH3COOH(solv) + CH3CH2OH(solv) ⇌ CH3COOCH2CH3(solv) + H2O(solv) where “(solv)” indicates that all reactants and products arein solution but not an aqueous solution. The equilibriumconstant for this reaction at 55 °C is 6.68. A pharmaceuticalchemist makes up 15.0 L of a solution that is initially0.275 M in acetic acid and 3.85 M in ethanol. At equilibrium,how many grams of ethyl acetate are formed?
- Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides.One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(C2H5)3). 3SnCl4 + 4Al(C2H5)3 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.230 L of SnCl4 (d = 2.226 g/mL) was treated with 0.396 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). If 0.335 L of tetraethylstannane (d = 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?One possible way of determining the identity of an alkene, is to let itundergo an oxidative cleavage reaction in the presence of hot basicpotassium permanganate. You are given two containers said to containdifferent alkenes. Container A is marked as cis / trans‐2‐butene andcontainer B as 2‐methyl‐1‐butene. Explain by referring to the formation ofproducts, how you would verify the identity of the alkenes.the products of the following reaction at 0oC. Indicate the major and minor products.
- Calculate the % yield-show work in a clear organized matter-be aware of significant figures. Which is the limiting reagent? A Freidel – Crafts Alkylation Name_______________ Data: Alkyl chloride used________tert-butyl chloride___________________________________ Mass alkyl chloride____15.7549 g_______________________________________ Mass 1,4-dimethoxybenzene_____5.0035 g_______________________________ Mass product isolated____2.7834 g______________________________________ Appearance of product__________dry snow white solid________________________________ m.p. rextal product__101 deg Celsius ____________________________________________ Published m.p. product____102-104 o C_____________ source____Chemspider________________ Name of product__1,4-di-tert-butyl-2,5-dimethoxybenzene._______________________________________________Describe Suprafacial and Antarafacial Rearrangement:Write out the reaction of Bromination of E-stilbene using chemdraw (ACS 1996 format). Include all reagents, products, solvents, reaction temperature and yield. Reagents used include glacial acetic acid, E-stilbene, and pyridinium perbromide, otherwise known as PHPB. Glacial acetic acid: 10mL Stilbene: 0.5g Perbromide: 1.0g Product yield (Precipitate) weight: 0.63g
- 2A---> 2B + C (Kp1) 2D---> 2E + C (Kp2) Now find the corresponding Kp3= f(Kp1, Kp2) = ?for this reaction: D + B----> A + E elaborate throughly with every step and annotationChoose the correct steps in the dehydration of secondary alcohol; then, arrange inchronological order.I - Formation of AlkeneII - Formation of AldehydeIII - Formation of Protonated alcoholIV - Undergoes E2 mechanismV-Undergoes E1 mechanismA. V-III-IB. IV-III-IIC. III-V-ID.III-IV-II Ethanol is heated with an acidified potassium manganate (VII) solution. What would be theproduct of this reaction?A. EthanalB. EtheneC. Ethanoic acidD. Ethane ALL of the following Ether can be prepared by Williamson's method, EXCEPT:A. Ditertbutyl etherB. Ethyl-tert-butyl etherC. anisoleD. Both A & B. Which of the following is not true of SN1 reactions?A. They are favored by nonpolar solvents.B. The concentration of nucleophiles does not affect the rate of reaction.C. Tertiary alkyl halides generally react through this mechanism.D. They occur through a 2-step concerted reaction. Butan-1-ol is formed from which of the following reactant-reaction pairs?A. Butanal - reduction reactionB. Butanone -…Using differences in C-H bond dissociation energies, calculate approximate selectivities secondary vs primary halogenation for the following compouond at 0o C. Be sure to include numberical differences.
