Potassium chlorate upon heating melts at 355 °C and decomposes at 480 °C. In the presence of MnOzcs) catalyst, KCI03(5) completely decomposes into Oz(®) and KCl(s). However, MnOz(s) itself does not take part in the overall chemical reaction. In an experiment to determine the gas constant, 1.300 g of pure KCIO3(s) and 100. mg of MnO2(s) were mixed in a testube and heated over a bunsen burner. The resulting Oz(g) product was bubbled in distilled water that is at exactly 25 °C (or 298.15 K) and collected in a 100-mL eudiometer. The experiment was done under a barometric pressure of 755 torr. The vapor pressure of water vapor at 25 °C is 23.8 mmHg.

Chemistry: Principles and Reactions
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Chapter5: Gases
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Problem 33QAP: Dichlorine oxide is used as bactericide to purify water. It is produced by the chlorination of...
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Potassium chlorate upon heating melts at 355°C and decomposes at 480 °C. In
the presence of MnO2(s) catalyst, KC103(5) completely decomposes into O2(g) and
KC(6). However, MnO2(s) itself does not take part in the overall chemical reaction.
In an experiment to determine the gas constant, 1.300 g of pure KC1O3(s) and 100.
mg of MnO2(s) were mixed in a testube and heated over a bunsen burner. The
resulting Oz(g) product was bubbled in distilled water that is at exactly 25 °C (or
298.15 K) and collected in a 100-mL eudiometer. The experiment was done
under a barometric pressure of 755 torr. The vapor pressure of water vapor at
25 °C is 23.8 mmHg.
O2
Transcribed Image Text:Potassium chlorate upon heating melts at 355°C and decomposes at 480 °C. In the presence of MnO2(s) catalyst, KC103(5) completely decomposes into O2(g) and KC(6). However, MnO2(s) itself does not take part in the overall chemical reaction. In an experiment to determine the gas constant, 1.300 g of pure KC1O3(s) and 100. mg of MnO2(s) were mixed in a testube and heated over a bunsen burner. The resulting Oz(g) product was bubbled in distilled water that is at exactly 25 °C (or 298.15 K) and collected in a 100-mL eudiometer. The experiment was done under a barometric pressure of 755 torr. The vapor pressure of water vapor at 25 °C is 23.8 mmHg. O2
the liquid inside the eudiometer rests 1.36 cm below the water level in the
reservoir. The graduation on the eudiometer (not shown here) indicates that the
trapped gas is 88.57 mL. (10 pts)
a. Using the mass of the testube contents before and after the reaction, calculate
the number of moles of O2(g) [MW = 31.9988 g/mol] gas produced. (3pts)
b. Determine the pressure of the trapped gas inside the eudiometer in mmHg.
(2 pts)
c. Determine the partial pressure of the collected O2 in mm Hg. (1pt)
%3D
Transcribed Image Text:the liquid inside the eudiometer rests 1.36 cm below the water level in the reservoir. The graduation on the eudiometer (not shown here) indicates that the trapped gas is 88.57 mL. (10 pts) a. Using the mass of the testube contents before and after the reaction, calculate the number of moles of O2(g) [MW = 31.9988 g/mol] gas produced. (3pts) b. Determine the pressure of the trapped gas inside the eudiometer in mmHg. (2 pts) c. Determine the partial pressure of the collected O2 in mm Hg. (1pt) %3D
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