Practice for a Kinetics of the lodine-Clock Reaction

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter8: Sampling, Standardization, And Calibration
Section: Chapter Questions
Problem 8.19QAP
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Practice lab work 

Practice for a Kinetics of the lodine-Clock Reaction
Na2S2O3(0.005M)
Run 1
Run 2
Run 3
Run 4
Quantity.
[Na2S2O3] stock
[KI] stock
[H202] stock
k'
Run#
1
2
3
4
1drops
1drops
1drops
1 drop
Value
5.00*10^-3
2.00 * 10^-1
1.00* 10^-3
0.0289
Trial 1 (s)
0:34
0:07
1:11
0:12
KI(0.1M)
2 drops
Odrops
0 drops
0 drops
Trial 1 (s)
0:32
0:06
1:01
0:10
Trial 1 (s)
0:32
0:05
0:59
0:17
KI(0.2M)
0 drops
2 drops
2 drops
2 drops
Trial 1 (s)
0:23
0:04
1:06
0:09
H2O2(0.05M)
0 drops
0 drops
1 drops
0 drop
Trial 1 (s)
0:14
0:3
01:13
0:13
H2O2(0.1M)
2 drops
2 drops
0 drops
1 drop
Transcribed Image Text:Practice for a Kinetics of the lodine-Clock Reaction Na2S2O3(0.005M) Run 1 Run 2 Run 3 Run 4 Quantity. [Na2S2O3] stock [KI] stock [H202] stock k' Run# 1 2 3 4 1drops 1drops 1drops 1 drop Value 5.00*10^-3 2.00 * 10^-1 1.00* 10^-3 0.0289 Trial 1 (s) 0:34 0:07 1:11 0:12 KI(0.1M) 2 drops Odrops 0 drops 0 drops Trial 1 (s) 0:32 0:06 1:01 0:10 Trial 1 (s) 0:32 0:05 0:59 0:17 KI(0.2M) 0 drops 2 drops 2 drops 2 drops Trial 1 (s) 0:23 0:04 1:06 0:09 H2O2(0.05M) 0 drops 0 drops 1 drops 0 drop Trial 1 (s) 0:14 0:3 01:13 0:13 H2O2(0.1M) 2 drops 2 drops 0 drops 1 drop
Run 1
Run 2
Run 3
Run 4
Average time (s)
[H₂O₂]0 (M)
Table 2: Pseudo-rate constants from experimental data
Run 1
Run 2
Run 3
Run 4
[I]o (M)
Average:
[S₂O3²-10 (M)
k' (indicate units)
Average Rate of
Reaction (M/s)
Transcribed Image Text:Run 1 Run 2 Run 3 Run 4 Average time (s) [H₂O₂]0 (M) Table 2: Pseudo-rate constants from experimental data Run 1 Run 2 Run 3 Run 4 [I]o (M) Average: [S₂O3²-10 (M) k' (indicate units) Average Rate of Reaction (M/s)
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Calculate the initial [S₂O32] on the paper ([S₂O32-10), assuming the amount of S₂O3² you added
initially was diluted through the total volume of all reagents added to the paper:
Transcribed Image Text:Calculate the initial [S₂O32] on the paper ([S₂O32-10), assuming the amount of S₂O3² you added initially was diluted through the total volume of all reagents added to the paper:
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