Referring to the attached information, select the TRUE statements: (I) The bromide ion acts as a catalyst. (II) The steady state approximation can be applied to the bromide ion. (III) It is a heterogeneous catalysis. (IV) The maximum point of the graph in the reaction energy profile corresponds to the slow stage. (V) The reaction is catalyzed by the protonated cation of nitrous acid. (VI) All direct reactions are elementary and of order two.

Chemistry for Engineering Students
3rd Edition
ISBN:9781285199023
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
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Referring to the attached information, select the TRUE statements: (I) The bromide ion acts as a catalyst. (II) The steady state approximation can be applied to the bromide ion. (III) It is a heterogeneous catalysis. (IV) The maximum point of the graph in the reaction energy profile corresponds to the slow stage. (V) The reaction is catalyzed by the protonated cation of nitrous acid. (VI) All direct reactions are elementary and of order two.

La ley de velocidad para la reacción entre ácido nitroso (HNO,)
y anilina (C,H,NH,) es:
r= k,[H*][HNO,][Br ]
Se propone el mecanismo siguiente:
H* + HNO2
H,NO,*
equilibrio rápido
H,NO,* + Br- *?, ONBR + H,0
lenta
ONBr + CgH;NH2
ka
→ C;H;N2* + H,0 + Br-
rápida
Transcribed Image Text:La ley de velocidad para la reacción entre ácido nitroso (HNO,) y anilina (C,H,NH,) es: r= k,[H*][HNO,][Br ] Se propone el mecanismo siguiente: H* + HNO2 H,NO,* equilibrio rápido H,NO,* + Br- *?, ONBR + H,0 lenta ONBr + CgH;NH2 ka → C;H;N2* + H,0 + Br- rápida
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