Predict the products of the following reactions: (a) (b) (c) CI + NaOH OCH 3 NH₂ + NaOH + NaCl Te of your answers and attach to this assignment.
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- the compound B C23H46,a sex attractant of the common housefly,gave two products Ch3(cH2)12COOH and CH3(CH2)7COOH. Based on this information, suggest the likely structures of BCompound A, C5H10O, is one of the basic building blocks of nature. All steroids ans many other naturally occurring compounds are built from compound A. Spectroscopic analysis of A yields the following information. a) how many double bonds and/or rings does A have? b) From the IR spectrum, what is the identity of the oxygen-conataining functional group? c) what kinds of protons are responsible for the NMR absorptions listed d) propose a structure for ACompound A (C5H8) readily reacts with bromine (Br2) at room temperature to discharge the purple colour of bromine and form Compound B (C5H8Br2). When Compound A is treated with H2 in the presence of a transition metal catalyst, it is converted to compound C (C5H10). When treated with HCl, compound A is converted to compound D (C5H9Cl). B, Cand D are saturated compounds. Given this information, propose structural formulas for compounds A, B, C, and D.
- On being heated with a solution of sodium ethoxide in ethanol, compound A (C7H15Br) yielded a mixture of two alkenes B and C, each having the molecular formula C7H14. Catalytic hydrogenation of the major isomer B or the minor isomer C gave only 3-ethylpentane. Suggest structures for compounds A, B, and C consistent with these observations.From the following 1H-NMR and 13C-NMR spectra, assign a structure for a compound with a formula of C4H9Br. Give reasons (explanations) for the choosen structure.Explain why the hydrolysis of [Co(NH3)5Cl]2+ in the presence of base muchfaster than that of [Co(py)5Cl]2+? Illustrate your answer with suitable diagrams.
- Following is a structural formula for guanidine, the compound by which migratory birds excrete excess metabolic nitrogen. The hydrochloride salt of this compound is a white crystalline powder, freely soluble in water and ethanol. Q. Does proton transfer to guanidine occur preferentially to one of its -NH2 groups (cation A) or to its =NH group (cation B)? Explain.Hydrocarbon S, C8H8 reacts with hydrogen in the presence of platinum catalyst to yield T, C8H10. Compound U is formed when T is heated with alkaline potassium permanganate solution, followed by hydrolysis. The reaction of S with hydrogen bromide V, whereas ozonolysis of S produces W and methanal. Draw the structures of S to W. Give the name of the reaction for the conversion of S to T. Write all chemical equations involved.The compound acetophenone has a very similar molar mass to that of benzoic acid and benzamide. However, acetophenone has a much lower m.p. (20 °C) than both such that, by contrast, it is a liquid at room temperature. By considering intermolecular forces and comparing functional group structure, account for this big difference in physical properties.
- 3. The reaction of bromine with 3-hexanone produces two isomeric products of formula C6H11BrO. Give the mechanism for obtaining the two isomers.Compound A (C6H12O2) reacts with water, acid, and heatto yield compound B (C5H10O2) and compound C (CH4O).Compound B is acidic. Deduce possible structures of compounds A, B, and CWhat can you conclude regarding the difference in degree of acidity and alkalinity between organic and inorganic compounds? ( sample substances are dilute hcl, dilute acetic acid, dilute nh4oh and aniline).