Can you show the mechanism and do you any rules that will allow you to determine the answer without the mechanism? And any other information

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter19: Eas: Electrophilic Aromatic Substitution
Section: Chapter Questions
Problem 45E
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Can you show the mechanism and do you any rules that will allow you to determine the answer without the mechanism? And any other information

3.
4.
Problem Set: Start with benzene and provide all steps and reagents for an efficient synthesize of each mea
H3C
NO₂
2
1.
2.
1.
CI
+
+
O
AICI 3
CL
CH3CI
AICI 3
NO 2
CI
Cl
AICI 3
AICI 3
CH3
2.
O
NH₂
NH₂
Br₂, AICI 3
HNO3
H₂SO4
(disregard
ortho isomer)
3.
Br
Br
CI
Cl2, AICI 3
HNO3 (X's)
H₂SO4
O₂N
O
Zn(Hg)
HCI
NO ₂
Br
4.
Zn(Hg)
HCI
CI
1. Sn, HCI
2. NaOH(aq)
6.
H₂N
Br
NBS
ROOR
CH3
CH3
CH3
O
(i) Fe, HCI
ကို အောင်နိုင်
(ii) NaOH(aq)
NO₂
NH₂
NH
O
OCH 3 5.
CI
Try this!
HNO3
H₂SO4
Br.
HNO 3
H₂SO4
Br
CI-
NH₂
CH3
alc. KOH
Br.
Try this!
NaQH
H₂
NO ₂
NO₂
CH3
NO₂
2
NH₂
NH
O
(i) NaNO₂, HCI, 0 °C
ii) H3PO₂
Target molecule
Transcribed Image Text:3. 4. Problem Set: Start with benzene and provide all steps and reagents for an efficient synthesize of each mea H3C NO₂ 2 1. 2. 1. CI + + O AICI 3 CL CH3CI AICI 3 NO 2 CI Cl AICI 3 AICI 3 CH3 2. O NH₂ NH₂ Br₂, AICI 3 HNO3 H₂SO4 (disregard ortho isomer) 3. Br Br CI Cl2, AICI 3 HNO3 (X's) H₂SO4 O₂N O Zn(Hg) HCI NO ₂ Br 4. Zn(Hg) HCI CI 1. Sn, HCI 2. NaOH(aq) 6. H₂N Br NBS ROOR CH3 CH3 CH3 O (i) Fe, HCI ကို အောင်နိုင် (ii) NaOH(aq) NO₂ NH₂ NH O OCH 3 5. CI Try this! HNO3 H₂SO4 Br. HNO 3 H₂SO4 Br CI- NH₂ CH3 alc. KOH Br. Try this! NaQH H₂ NO ₂ NO₂ CH3 NO₂ 2 NH₂ NH O (i) NaNO₂, HCI, 0 °C ii) H3PO₂ Target molecule
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