Propose a mechanism for the following reactionCH3CH31. (CF3CO0'),Hg, H2OCH3CHCHCH2CH3-CHCHCH32. NABH4ОН(CF;CO0),Hg, := mercuric trifluoroacetate

Given is oxymercuration demercuration reaction.

Answered: Propose a mechanism for the following…

Propose a mechanism for the following reaction CH3 CH3 1. (CF3CO0'),Hg, H2O CH3-CH CH CH2 CH3-CH CH CH 2. NaBH4 ОН (CF;CO0),Hg, : = mercuric trifluoroacetate

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter16: Aldehydes And Ketones

Section: Chapter Questions

Problem 16.58P: Propose a mechanism for this isomerization.

See similar textbooks

Related questions

Q: A D H,O* CH,CI H,SO, H;C B E KMNO, + + HNO, H AICI, AICI, A Cl, FeCl, F+G 7. Based on the reaction…

A: (7) (a) Structures of compounds A to H are -

Q: Suggest reagents suitable for carrying out each step in the following synthetic sequence. Br O÷X÷X…

Q: 1. NaNH/sivi NHy-78°C 1. NANH/sivi NH-78°C B(CHa) A( CHa) H-CEC-H 2. 1-Bromodekan 2.1-Bromo-5-metil…

Q: Me N. Meo OMe MeN- MeN- H...) -N- MeN- Br MeCN, 100 °C NaH, THF; Br H then 6M HCI MeO2C, -Me Me…

Q: Please show a detailed mechanism for the cleavage, in base, of propylene oxide, CH3-CH-CH2, to…

Q: Provide a mechanism for the following transformation. NH2 NaNO2/HCI/H,0 OH CH3 H3C- -CH3 H3C CH3 CH3…

A: Given : We have to make the product for the given reaction.

Q: 18. Suggest a plausible mechanism with structures of the following reaction: Br, H,0 CH3 CH2B.…

A: In the reaction mechanism of the above reaction, first the alkene will attack on the Br2 molecule as…

Q: (b) Suggest a plausible mechanism for the following transformations R EGN (1) →? (2) MezSiCl (3)…

A: NEt3 is base. It will absrtact proton from methylene group and will form enolate.Since Si is a hard…

Q: Which compound shows the highest rate of reaction when shaken vigorously with ethanolic silver…

Q: 5. Provide the mechanism for the Wittig reaction below. H3C H3C- FPPH3 CH3

A: The Wittig reaction is the chemical reaction of aldehyde or ketone with a triphenyl phosphonium…

Q: 26. Write reasonable mechanisms for each of the following transformations. H3C CH3 CH;CO,Na a) Br…

A: Applying concept of organic reaction and mechanism.

Q: a) Provide a mechanism that accounts for the product formed in the following reaction. OH CH +…

A: In both the reactions, carbocation rearrangement takes place through hydride shift

Q: OCH3 AICI3 + CH3¬Ĉ-O-Ĉ-CH3 CH3O- -CH3 + CH3¬Ĉ-OH CH;Az

Q: cess CHCH-C 1 KMKO, NaOH HO AICI, H$O. 2. H0

Q: MgBr O CI 2) H30* pyridine

A: See mechanism below.

Q: 3. Provide the mechanism for the following rxn: ethanol heat Br a. CH3 CH3 NAOCH3, CH3OH Br b. DH H.…

A: Mechanism of Elimination reaction:

Q: Osaw the Yeaction mechanisms for the reduction NABHU g benzshenone using Reduction (o.138g) NABH4…

Q: 4. Propose a plausible mechanism for the Wittig reaction and then the enol ether hydrolysis. ( H,C-O…

A: Since, you have asking multiple questions, so I will solved first question for you. You can see…

Q: B3. Write a detailed mechanism for the following Knorr Synthesis 1) (BUO-NO (0.5 equiv) , HCI A…

A: Preparation of pyrrole compound by using beta amino keto-ester and beta-keto ester is called Knorr…

Q: O,N. Br O2N

Q: The following transformation can be accomplished by using to make the product. 1) Br2, FeBr3 2) HBr,…

Q: What is the predominant mechanism of the reaction below? Br NaOCH3 CH3OH SN2 El E2

Q: Suggest likely a mechanism for the following reaction: PPO OPP- CH3

Q: H3C. NH,CI/NaCN HCI/H2O/Heat H3C. NH3 CH3 CH3 но

A: Here we have to write mechanism of the following multistep reactions.

Q: as below give identical products. oth products and the complete reaction mechanism including curved…

A: 1. Addition of water to alkyne : given alkyne is 2-Hexyne it is internal alkyne , if water is…

Q: НО ОН NaBH4 Cl3C CląC H H,0

A: Trichloroethanol may be prepared by the direct reduction of chloral hydrate in water with sodium…

Q: он pyridine 1. SOCI, SO2 ont Aqueous acetone H20 H3C HBr 2. H3C Br H OH optically active racemic a =…

A: The questions are based on the concept of organic chemistry. It involves determination of type of…

Q: Suggest a mechanism for the following reaction. Explain why NaB(CN)H3 is preferable to NABH4 as…

A: We have to suggest mechanism for the following reaction in step 2

Q: Give the major product of each of the following reactions: Bra d. CH,C=CCH, CH,I, excess HBr e.…

A: According to Markonikov's addition, the more electronegative part goes to the more substituted C in…

Q: write mechanism step by step for the reaction ?

A: The mechanism for the given reaction can be drawn as.

Q: (i) Provide the product for the reaction below. (ii) How would you know if the reaction was an SN1…

Q: Write a detailed mechanism for this transformation. OH HCI НО НО H2O -OH

Q: CI BiCl3 (5 mol%) CI D, 24 hrs.., neat CI

A: The objective of the question is to write the detailed mechanism of the given transformation. In…

Q: 2) Write a detailed mechanism for the following reaction: H2S04 CH;CH;C=CH + H,O CH;CH¿CCH3

Q: 2. Propose a stepwise mechanism for the following transformation, producing the observed…

A: Grignard reagent, RMgX is a useful reagent in organic synthesis. Where X be any halogen. Epoxides…

Q: The following transformation can be accomplished by using. to make the product. 1) Br2, FeBr3 2)…

A: -> First of all there occur friedel craft acylation reaction. Then there occur reduction .

Q: Write a detailed mechanism for the following reaction. KCN. HCN

Q: 2) Write a detailed mechanism for the following reaction: H2SO4 CH;CH,C=CH + H2O CH;CH,CCH3

A: Hydration reaction of Alkyne takes place in acidic medium as follows:

Q: Furfuryl ethyl ether (FEE) was identiied as a component that forms in aged beer, giving ita…

A: Protonated alcoholic group of furfuryl alcohol eliminates water molecule to produce carbocation…

Q: Give the mechanism (arrow-pushing) for the reaction below. NAOME/MEOH \Br b. Name the product of the…

A: The mechanism is provided below:

Q: This compound was made from a conjugated enone using a multi-step synthesis that included a direct…

A: The enone can give an addition reaction at C=C and C=O. The addition reaction at C=O is known as a…

Q: Provide the mechanism for the Wittig reaction below.* H3C H3C- PPh3 CH3

A: In organic chemistry, an aldehyde or ketone when react with wittig reagent ( phosphorus ylide) gives…

Q: Write a detailed mechanism for the following reaction. он Он H,SO4, H2O ÓH но

A: All steps mention in hand written solution.

Q: Write a detailed mechanism for this transformation но. HCI SH H20 H

Q: Which one of the following is not a mechanistic step in the hydrolysis of benzamide? -NH + :NH3 -OH…

Q: (a) Suggest the mechanism of the following reactions and comment on your choice of SN1 or SN2. ()…

A: Detail mechanism is shown below

Q: DMSO T = 100°C 29. CH,O in CH,OH at 100 degrees C 30. Br 31. ONLY PRODUCT

Q: 1. Give a mechanism of following conversion CH,OH

Q: 2) Provide the reagent(s) and the reaction mechanism of the following reaction. (* is the radio…

A: Detail mechanistic pathway is given below to find out the correct reagents for following conversion

Q: 6. Provide a total synthesis for the target molecule starting from benzene using any reagents…

A: (a) When acetone is treated with phenyl magnesium Bromide (Grignard reagent) then 2-phenyl -2-…

Question

Propose a mechanism for the following reaction
CH3
CH3
1. (CF3CO0'),Hg, H2O
CH3
CH
CH
CH2
CH3-CH
CH
CH3
2. NABH4
ОН
(CF;CO0),Hg, :
= mercuric trifluoroacetate

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Propose a mechanism for the followingreaction.
Illustrate the Dehydration of a 1° ROH—An E2 Mechanism ?
Propose a mechanism for this isomerization.
Show how the synthetic scheme developed in Problem 23.67 can be modified to synthesize this triiodobenzoic acid X-ray contrast agent.
Optically active 2-bromobutane undergoes racemization on treatment with a solution of KBr. Give a mechanism for this racemization
Explain the E2 mechanism (bimolecular elimination) of of Elimination ?
The reaction of 2-ethyl-1-pentene with Br2, with H2 + Pd/C, or with R2BH/THF followed by aqueous HO- + H2O2 leads to a racemic mixture. Explain why a racemic mixture is obtained in each case.
Propose a detailed mechanism for the transformations presented. represent the Intermediate structure A.
Please describe the difference in the outcome of treating a terminal alkyne with HgSO4, H2SO4, H2O and with 9-BBN, followed by H2O2 and NaOH.
The (+) - aureol is a natural product that has shown selective activity against certain colon and lung cancer cell lines. It is postulated that a key step in the biosynthesis of this substance is the conversion of carbocation A into B. Propose a possible mechanism for this transformation (MUST show the corresponding arrows).
(a) What happens when CH3—O—CH<sub3 is heated with HI?(b) Explain mechanism for hydration of acid catalyzed ethene :CH2 = CH2 + HzO CH3—CH,—OH
The methoxy group (-OCH3) group is considered a .... Ortho/Para Directing Activator Ortho/Para Directing Deactivator Meta Directing Deactivator