Discuss every labelled peak in the IR spectrum and identify functional group using the provided table 15.2 (Wavenumbers). TABLE 15.2 IMPORTANT SIGNALS IN IR SPECTROSCOPYFREQUENCY (cm 1)FREQUENCY (cm)STRUCTURAL UNITSTRUCTURAL UNITUSEFUL SIGNALS IN THE DIAGNOSTIC REGIONSingle Bonds (X-H)Double BondsO-H3200-3600C=01750-18500-H2200-3600ROC=O1700-1750N-H3350-3500ноEC-H~3300C=O1700-1750R3000-3100Rc=OR1680-1750-C-H2850-3000H,NC=O1650-1700RC-H2750-2850C=C1600-1700Triple BondsCEC-2100-22001450-16001650-2000CEN2200-2300 Q.1. Complete the following equations. Draw structural formula of the major product formedand write IUPAC names1.H*+H20?2.Zn++ 0,H*3.H2C=CH2 + KMNO,→ ?4.Ag catalyst?H2C=CH2 + O2250 °C5.catalystn H2C=CH2?ROOR1000 atm, > 100 °C6.H3C-CH2-CI + NH3?

1. Acid catalyzed hydration of alkenes. 2. Ozonolysis. 3. Alkenes reaction with Hot KMnO4. 4.…

Q.1. Complete the following equations. Draw structural formula of the major product formed and write IUPAC names 1. H* + H20 2. Zn + O3 H* H2C=CH2 + KMNO. 4. H2C=CH2 + O, Ag catalyst ? 250 °C catalyst n H2C=CH2 ? ROOR 1000 atm, > 100 °C H3C-CH2-CI + NH3 ? 3. 5. 6.

Q.1. Complete the following equations. Draw structural formula of the major product formed and write IUPAC names 1. H* + H20 2. Zn + O3 H* H2C=CH2 + KMNO. 4. H2C=CH2 + O, Ag catalyst ? 250 °C catalyst n H2C=CH2 ? ROOR 1000 atm, > 100 °C H3C-CH2-CI + NH3 ? 3. 5. 6.

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter6: Alkanes & Alkenes

Section: Chapter Questions

Problem 33CTQ

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Question

Discuss every labelled peak in the IR spectrum and identify functional group using the provided table 15.2 (Wavenumbers).

TABLE 15.2 IMPORTANT SIGNALS IN IR SPECTROSCOPY
FREQUENCY (cm 1)
FREQUENCY (cm)
STRUCTURAL UNIT
STRUCTURAL UNIT
USEFUL SIGNALS IN THE DIAGNOSTIC REGION
Single Bonds (X-H)
Double Bonds
O-H
3200-3600
C=0
1750-1850
0-H
2200-3600
RO
C=O
1700-1750
N-H
3350-3500
но
EC-H
~3300
C=O
1700-1750
R
3000-3100
R
c=O
R
1680-1750
-C-H
2850-3000
H,N
C=O
1650-1700
R
C-H
2750-2850
C=C
1600-1700
Triple Bonds
CEC-
2100-2200
1450-1600
1650-2000
CEN
2200-2300

Q.1. Complete the following equations. Draw structural formula of the major product formed
and write IUPAC names
1.
H*
+
H20
?
2.
Zn
+
+ 0,
H*
3.
H2C=CH2 + KMNO,
→ ?
4.
Ag catalyst
?
H2C=CH2 + O2
250 °C
5.
catalyst
n H2C=CH2
?
ROOR
1000 atm, > 100 °C
6.
H3C-CH2-CI + NH3
?

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