Please do all 06. Predict the major product(s) of the following reactions. Show stereochemistry whereapplicable.KOC(CH3)3(a)(CH₂) COHOHH₂O*(b)O6(e)(9)(h)BrBr₂H₂O1. Hg(OAc)₂, H₂O2. NaBH₂mCPBACH₂Cl₂KMnO4 (warm)OHOs04H₂O₂KOHCH₂CH₂OH, A(END)

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Answered: Q6. Predict the major product(s) of the…

Q6. Predict the major product(s) of the following reactions. Show stereochemistry where applicable. or (a) KOC(CH₂) (CH₂)COH H₂O* (b) (c) HON Br₂ H₂O

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter11: Reactions Of Alkyl Halides: Nucleophilic Substitutions And Eliminations

Section11.SE: Something Extra

Problem 54AP

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Concept explainers

Reactions of Ethers

Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.

Epoxides

Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.

Williamson Ether Synthesis

An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.

Question

Please do all

06. Predict the major product(s) of the following reactions. Show stereochemistry where
applicable.
KOC(CH3)3
(a)
(CH₂) COH
OH
H₂O*
(b)
O
6
(e)
(9)
(h)
Br
Br₂
H₂O
1. Hg(OAc)₂, H₂O
2. NaBH₂
mCPBA
CH₂Cl₂
KMnO4 (warm)
OH
Os04
H₂O₂
KOH
CH₂CH₂OH, A
(END)

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