Question 8 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. (CH3)2S Br2 CH₂OH BOH 1.03 2. DMS KMnO4, NaOH cold HI 20 Pd or Pt (catalyst) HBr ROOR (peroxide) Н2О H₂SO4 MCPBA 1. Os04 2. H₂O2 CH3CO₂H (peroxyacid) 17 16 15 MCPBA MCPBA H3O+ 14 18 12 11 10 D₂ (deuterium) Pd or Ni (catalyst) Br2 H₂O BH3⚫THF Bra HCI 1. BH3.THF 2. H₂O2, NaOH Br2 A B 0 D Br ď ď OH Br + Br OH Br "OH Br "Br OH ď ď ď ď "OH 'Br OH Br A B C D
Question 8 Please predict the products for each of the following reactions. Clearly show the regiochemistry (Markovnikov vs anti-Markovnikov) and stereochemistry (syn- vs anti- or both). If a mixture of enantiomers is formed, please draw all the enantiomers. (CH3)2S Br2 CH₂OH BOH 1.03 2. DMS KMnO4, NaOH cold HI 20 Pd or Pt (catalyst) HBr ROOR (peroxide) Н2О H₂SO4 MCPBA 1. Os04 2. H₂O2 CH3CO₂H (peroxyacid) 17 16 15 MCPBA MCPBA H3O+ 14 18 12 11 10 D₂ (deuterium) Pd or Ni (catalyst) Br2 H₂O BH3⚫THF Bra HCI 1. BH3.THF 2. H₂O2, NaOH Br2 A B 0 D Br ď ď OH Br + Br OH Br "OH Br "Br OH ď ď ď ď "OH 'Br OH Br A B C D
Chapter9: Alkynes: An Introduction To Organic Synthesis
Section9.SE: Something Extra
Problem 46AP: A hydrocarbon of unknown structure has the formula C8H10. On catalytic hydrogenation over the...
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