Rank the following atoms in order of increasing first ionization energies (i.e., lowest to highest): Rb, F, Mg, B, N. A) F < N < B < Mg < Rb B) Rb < Mg < F B > N > F > Mg
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- Identify the element that corresponds to each of the simplified photoelectron spectral data given below. (Energy data taken from D. A. Shirley, R. L Martin, S. P. Kowalczyk. F. R. McFeely, and L. Ley: Core-electron binding energies of the first thirty elements, Physical Review B, Vol. 15, pp. 544-552, 1977.) (a) There are peaks at energies of 64.8 and 5.4 eV, corresponding to 2 and 1 electrons, respectively. (b) There are peaks at energies of 3614, 384, 301, 40.9, 24.7, and 4.34 eV, corresponding to 2, 2, 6, 2, 6, and 1 electrons, respectively. (c) There are peaks at energies of 4494, 503, 404, 56.4, 33.6, 8.01, and 6.65 eV, corresponding to 2, 2, 6, 2, 6, 1, and 2 electrons, respectively.Predict the larger ion in each of the following pairs. Give reasons for your answers. (a) O,S2 (b) Co2+,Ti2+ (c) Mn2+,Mn4+ (d) Ca2+,Sr2+Identify the element that corresponds to each of the simplified photoelectron spectral data given below. (Energy data taken from D. A. Shirley, R. L. Martin, S. P. Kowalczyk. F. R. McFeely, and L Ley: Core-electron binding energies of the first thirty elements Physical Review B, Vol. 15, pp. 544-552, 1977.) (a) There are peaks at energies corresponding to 1079, 70.8, 38.0, 5.14 eV, corresponding to 2, 2, 6, and 1 electrons, respectively. (b) There are peaks at energies corresponding to 4043, 443, 351, 48.4, 30.1, and 6.11 eV, corresponding to 2, 2, 6, 2, 6, and 2 electrons, respectively. (c) There are peaks at energies corresponding to 5475, 638, 524, 77, 47, 12. and 7.3 eV, corresponding to 2, 2, 6, 2, 6, 3, and 2 electrons, respectively.
- (a) Predict the atomic number of the (as yet undiscovered) alkali-metal element in the eighth period. (b) Suppose the eighth-period alkali-metal atom turned out to have atomic number 137. What explanation would you give for such a high atomic number (recall that the atomic number of francium is only 87)?Answer the following questions, assuming that ms, could have three values rather than two and that the rules for n, l, and ml are the normal ones. a. How many electrons would an orbital be able to hold? b. How many elements would the first and second periods in the periodic table contain? c. How many elements would be contained in the first transition metal series? d. How many electrons would the set of 4f orbitals be able to bold?For each of the following pairs of atoms or ions, state which you expect to have the larger radius. (a) Sm or Sm3+ (b) Mg or Ca (c) I orXe (d) Ge or As (e) Sr+ or Rb
- The first ionization energies of As and Se are 0.947 and 0.941 MJ/mol, respectively. Rationalize these values in terms of electron configurations.Cesium is used extensively in photocells and in television cameras because it has the lowest ionization energy of all the stable elements. (a) What is the maximum kinetic energy of a photoelectron ejected from cesium by 520 nm light? Note that if the wavelength of the light used to irradiate the cesium surface becomes longer than 660 nm, no photoelectrons are emitted. (b) Use the rest mass of the electron to calculate the velocity of the photoelectron in (a).The energy needed to remove one electron from a gaseous potassium atom is only about two-thirds as much as that needed to remove one electron from a gaseous calcium atom, yet nearly three times as much energy as that needed to remove one electron from K+ as from Ca+ . What explanation can you give for this contrast? What do you expect to be the relation between the ionization energy of Ca+ and that of neutral K?
- Consider the representations of the p and d atomic orbitals in Figs. 2-15 and 2- 17. What do the + and signs indicate?The outermost electron in an alkali-metal atom is sometimes described as resembling an electron in the corresponding state of a one-electron atom. Compare the first ionization energy of lithium with the binding energy of a 2s electron in a one-electron atom that has nuclear charge Zeff , and determine the value of Zeff that is necessary for the two energies to agree. Repeat the calculation for the 3s electron of sodium and the 4s electron of potassium.For each of the following pairs of elements, choose the one that correctly completes the following table.