Reaction Scheme: y NO ON-OH oso3H -ÕH₂ HSO4 8 O=NO Betu H- HSO4 OCH3 O₂N nitronium OCH3 OCH3

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter8: Addition Via Carbocation
Section: Chapter Questions
Problem 3E: Explain why ethene does not react with HX ( X=Cl , Br or I) under normal conditions.
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Nitrating methyl benzoate. 1.Describe the mechanism of EAS clearly and in detail 2. What is the effect of subtituent of the outcome of EAS;include 3 classes of subtituents
Reaction Scheme:
ON-OH
NO
HOSO3H
-ÕH₂
HSO4
8
O=NO
Bete
H-
HSO4
OCH3
O₂N
nitronium
OCH3
OCH3
Transcribed Image Text:Reaction Scheme: ON-OH NO HOSO3H -ÕH₂ HSO4 8 O=NO Bete H- HSO4 OCH3 O₂N nitronium OCH3 OCH3
CH3O
+ No
m²
Least stable
CH3R
P-
+
CH30
•NO ₂
schoo
NO2
NO2
CHOREO
CH300
NO2
NO-
Least
Stable
_NO₂
+
lley College
NO₂
CHO
102
Why Meta position is
most
stable form
Electrophilic attack at either the ortho- or para-position
positive charge on the carbon that bears
places a
the substituent ((+30=0).
n
A
Transcribed Image Text:CH3O + No m² Least stable CH3R P- + CH30 •NO ₂ schoo NO2 NO2 CHOREO CH300 NO2 NO- Least Stable _NO₂ + lley College NO₂ CHO 102 Why Meta position is most stable form Electrophilic attack at either the ortho- or para-position positive charge on the carbon that bears places a the substituent ((+30=0). n A
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