A 10.0-ml sample of aqueous NaOCI is treated with excess KI in an acidic solution. The quantity of iodine that is liberated is such that 28.02 mL of 0.0250 M Na2S₂O, solution must be added to cause the disappearance of the dark blue color due to the starch indicator. What is the molarity of the solution of NaOCI?

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Chapter17: Electrochemistry
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Redo the third problem of the Prelaboratory Assignment, substituting NaIO3 (sodium iodate) for NaOCl. The new reaction yields I2 as the only product containing a halogen.

3.
A 10.0-mL sample of aqueous NaOCI is treated with excess KI in an acidic solution. The quantity
of iodine that is liberated is such that 28.02 mL of 0.0250 M Na₂S₂O3 solution must be added to
cause the disappearance of the dark blue color due to the starch indicator. What is the molarity of
the solution of NaOCI?
# of moles of Na2S203 = M*V= 0.0250 M * 28.02mL = 0.7005mmol
2. According to the balanced equation
2 moles of $203 2- reacts with 1 mole of CIO-
so 0.7005mmol of $203 2- reacts with 0.7005 mmol * 1/2 = 0.35025 mmol of CIO-
# of moles of NaOCI= 0.35025 mmol
volume = 10ml
Molarity of NaOCI=0.35025 mmol/ 10.0ml = 0.0350 M
Transcribed Image Text:3. A 10.0-mL sample of aqueous NaOCI is treated with excess KI in an acidic solution. The quantity of iodine that is liberated is such that 28.02 mL of 0.0250 M Na₂S₂O3 solution must be added to cause the disappearance of the dark blue color due to the starch indicator. What is the molarity of the solution of NaOCI? # of moles of Na2S203 = M*V= 0.0250 M * 28.02mL = 0.7005mmol 2. According to the balanced equation 2 moles of $203 2- reacts with 1 mole of CIO- so 0.7005mmol of $203 2- reacts with 0.7005 mmol * 1/2 = 0.35025 mmol of CIO- # of moles of NaOCI= 0.35025 mmol volume = 10ml Molarity of NaOCI=0.35025 mmol/ 10.0ml = 0.0350 M
The Strength of a Laundry Bleach
Prelaboratory Assignment
Write the balanced equations for the following oxidation-reduction reactions that you will
encounter in this experiment:
The reduction of CIO by I in acidic solution
1.
2.
a.
C1012H₂0+21Iz+CI+H₂O
b.
The reduction of I₂ by S₂O3 in acidic solution
2-
1₂+ 25 ₂0²² → 21+ Sad
What conversion factor will enable you to calculate the number of moles of ClO ions from the
number of moles of S₂O3 ions used in the titration?
2-
2 moles of $₂03 = 1 mole of
CIÓ
Transcribed Image Text:The Strength of a Laundry Bleach Prelaboratory Assignment Write the balanced equations for the following oxidation-reduction reactions that you will encounter in this experiment: The reduction of CIO by I in acidic solution 1. 2. a. C1012H₂0+21Iz+CI+H₂O b. The reduction of I₂ by S₂O3 in acidic solution 2- 1₂+ 25 ₂0²² → 21+ Sad What conversion factor will enable you to calculate the number of moles of ClO ions from the number of moles of S₂O3 ions used in the titration? 2- 2 moles of $₂03 = 1 mole of CIÓ
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Redo the third problem of the Prelaboratory Assignment, substituting NaIO3 (sodium iodate) for NaOCl. The new reaction yields I2 as the only product containing a halogen?

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