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- give a primary organic product(s) for each reaction shownIn an attempt to prepare propylbenzene, a chemist alkylated benzene with 1-chloropropane and aluminum chloride. However, two isomeric hydrocarbons were obtained in the proportion of 2: 1. What is the main product? How did this come about? Explain showing the mechanism and nomenclature of the reaction compoundsReaction of 2° alcohol A with HCl forms three alkyl chlorides, all of which result from rearrangement of the 2° carbocation initially formed. Draw the structures of these products and a mechanism that illustrates how each is formed.
- (a) What happens when CH3—O—CH<sub3 is heated with HI?(b) Explain mechanism for hydration of acid catalyzed ethene :CH2 = CH2 + HzO CH3—CH,—OHShow the complete arrow pushing mechanism for this reaction and explain the originof the stereochemistry observed in the product.In SN2 reactions of haloalkanes, the order of reactivity is RI>RBr>RCl>RF. Alkyl iodides are considerably more reactive than alkyl fluorides, often by factors as great as 106. All 1-halo-2,4-dinitrobenzenes, however, react at approximately the same rate in nucleophilic aromatic substitutions. Account for this difference in relative reactivities.
- Identify the major product/S of these reactions:When 3-methyl-1-butene is reacted with 9-borabicyclo[3.3.1]nonane, the "1-ol" product is formed. What is the detailed reactin scheme for the transformation? Describe the purification procedure.The replacement of CH3OH to dimethyl sulfoxide, DMSO (CH3)2S=O) as a solvent in the substitution reaction below results in what?