Show the reaction mechanism when phenol is reaction with a solution of Br2 and glacial acetic acid.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter18: Functional Derivatives Of Carboxylic Acids
Section: Chapter Questions
Problem 18.37P
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Show the reaction mechanism when phenol is reaction with a solution of Br2 and glacial acetic acid.

Expert Solution
Step 1

Phenol reacts with bromine and undergoes bromination reaction to produce p-bromophenol as major product and o-bromophenol as minor product.

And if the bromine is present in excess, the product forming will be 2,4,6-tribromophenol.

 

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