Sodium benzoate, the sodium salt of benzoic acid, is used as a food preservative. A sample containing solid sodium benzoate mixed with sodium chloride is dissolved in 50.0 mL of 0.500 M HCl, giving an acidic solution (benzoic acid mixed with HCl). This mixture is then titrated with 0.393 M NaOH. After the addition of 46.50 mL of the NaOH solution, the pH is found to be 8.2. At this point, the addition of one more drop (0.02 mL) of NaOH raises the pH to 9.3. Calculate the mass of sodium benzoate (NaC6H5COO) in the original sample. (Hint: At the equivalence point, the total number of moles of acid [here HCl] equals the total number of moles of base [here, both NaOH and NaC6H5COO].)
Sodium benzoate, the sodium salt of benzoic acid, is used as a food preservative. A sample containing solid sodium benzoate mixed with sodium chloride is dissolved in 50.0 mL of 0.500 M HCl, giving an acidic solution (benzoic acid mixed with HCl). This mixture is then titrated with 0.393 M NaOH. After the addition of 46.50 mL of the NaOH solution, the pH is found to be 8.2. At this point, the addition of one more drop (0.02 mL) of NaOH raises the pH to 9.3. Calculate the mass of sodium benzoate (NaC6H5COO) in the original sample. (Hint: At the equivalence point, the total number of moles of acid [here HCl] equals the total number of moles of base [here, both NaOH and NaC6H5COO].)
Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter15: Acid–base Equilibria
Section: Chapter Questions
Problem 57P
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Sodium benzoate, the sodium salt of benzoic acid, is used as a food preservative. A sample containing solid sodium benzoate mixed with sodium chloride is dissolved in 50.0 mL of 0.500 M HCl, giving an acidic solution (benzoic acid mixed with HCl). This mixture is then titrated with 0.393 M NaOH. After the addition of 46.50 mL of the NaOH solution, the pH is found to be 8.2. At this point, the addition of one more drop (0.02 mL) of NaOH raises the pH to 9.3. Calculate the mass of sodium benzoate (NaC6H5COO) in the original sample. (Hint: At the equivalence point, the total number of moles of acid [here HCl] equals the total number of moles of base [here, both NaOH and NaC6H5COO].)
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