solubliky in aqueous solution changes with pH. If the solubility does change, pick the pH at which you'd expect the highest solubility. You'll find K, data in the ALEKS Data tab. compound caco MFC1 BACO, Does solubility change with PH? yes Ⓒ no O yas O no Ⓒyes Om pH = 4 D highest solubility pH = 6 pH = 7
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- Professor Acetico Acido has assigned the analysis of unknown organic compound samples to Al Coholbased on their solubility behavior. The summary of the solubility profile are tabulated below along with thepossible structures of the samples. Identify each unknown sample by matching the respective solubility profilewith the given structures. Briefly explain the reason for your answer.TypeFormulaKsp Solubility Product Constants (Ksp at 25 oC) TypeFormulaKspBromidesPbBr26.3 × 10-6AgBr3.3 × 10-13CarbonatesBaCO38.1 × 10-9CaCO33.8 × 10-9CoCO38.0 × 10-13CuCO32.5 × 10-10FeCO33.5 × 10-11PbCO31.5 × 10-13MgCO34.0 × 10-5MnCO31.8 × 10-11NiCO36.6 × 10-9Ag2CO38.1 × 10-12ZnCO31.5 × 10-11ChloridesPbCl21.7 × 10-5AgCl1.8 × 10-10ChromatesBaCrO42.0 × 10-10CaCrO47.1 × 10-4PbCrO41.8 × 10-14Ag2CrO49.0 × 10-12CyanidesNi(CN)23.0 × 10-23AgCN1.2 × 10-16Zn(CN)28.0 × 10-12FluoridesBaF21.7 × 10-6CaF23.9 × 10-11PbF23.7 × 10-8MgF26.4 × 10-9HydroxidesAgOH2.0 × 10-8Al(OH)31.9 × 10-33Ca(OH)27.9 × 10-6Cr(OH)36.7 × 10-31Co(OH)22.5 × 10-16Cu(OH)21.6 × 10-19Fe(OH)27.9 × 10-15Fe(OH)36.3 × 10-38Pb(OH)22.8 × 10-16Mg(OH)21.5 × 10-11Mn(OH)24.6 × 10-14Ni(OH)22.8 × 10-16Zn(OH)24.5 × 10-17IodidesPbI28.7 × 10-9AgI1.5 × 10-16OxalatesBaC2O41.1 × 10-7CaC2O42.3 × 10-9MgC2O48.6 × 10-5PhosphatesAlPO41.3 × 10-20Ba3(PO4)21.3 × 10-29Ca3(PO4)21.0 × 10-25CrPO42.4 × 10-23Pb3(PO4)23.0 × 10-44Ag3PO41.3 × 10-20Zn3(PO4)29.1 ×…1.1The Ksp of Ca3 (PO4 ) 2 is 1.3 × 10−26 . Estimate the solubility of this salt in units of g. L −1 . You must show any reaction equation(s) that you may think are necessary. 1.2 If a sample of solid Ca3(PO4)2 is stirred into exactly one litre of a 0.550M solution of Na3PO4, how will the solubility of the salt compare with the answer that you have obtained in question 1.1? Explain you answer in a short sentence.
- In order to prepare for a qualitative analysis experiment, Felix is predicting whether small samples of several pairs of 0.10 M control solutions will form a precipitate when mixed. He uses the table of solubility values provided as well as the general solubility guidelines in the chempendix. Solubilities of Alkaline Earth Salts (g/100 g H2O, at 20−25∘C) OH− CO2−3 SO2−4 CrO2−4 C2O2−4 Mg2+ 0.00069 0.18 35.7 54.8 0.038Ca2+ 0.16 0.00066 0.205 13.2 0.00061Sr2+ 2.25 0.00034 0.135 0.106 0.005Ba2+ 4.91 0.0014 0.00031 0.00026 0.0075For each pair of compounds, predict the formula for the precipitate that Felix will see when he mixes the solutions in lab. If no precipitate forms, enter NP for no precipitate.Ca3(PO4)2(s) is used as a calcium supplement in foods. Due to its low solubility (Ksp = 1.08 x10-23) it forms colloids as an additive to plant based milks. Ca3(PO4)2 (s) = 3 Ca2+ (aq) + 2 PO43- (aq) - Calculate the molar solubility of in an aqueous solution of 0.100 M Na3(PO4) (in mol L-1). - Would the addition of a 0.500 M 100 mL aqueous solution of CaCly to a 0.500 M 200 mL agueous solution of Na3(PO4) precipitate Ca3(PO4)2?Show some working1. Write the dissociation reaction and solubility product constant expression for the following sparingly soluble salt. a. AgBr Ksp = 5.2 x 10-13 b. PbCl2 Ksp = 1.7 x 10-5 2. Determine the Molar Solubility of the following sparingly soluble salt in water. a. AgBr Ksp = 5.2 x 10-13 b. PbCl2 Ksp = 1.7 x 10-5 3. Express the solubility (S) in question #2 in g/L. 4. Calculate Ksp for the ff. substances, given the molar concentration of their saturated solution. a. Ag2C2O4 ( S= 2.06 x 10-4 ) b. Al(OH)3 ( S = 1.82 x 10-9 ) 5. Calculate the molar solubility of the salts in problem #2 for the solution in which the cation concentration is 0.050 M.
- 1. The Ksp of Ca3(PO4)2 is 1.3 × 10−26. Estimate the solubility of this salt in units of g. L−12. If a sample of solid Ca3(PO4)2 is stirred into exactly one litre of a 0.550M solution of Na3PO4, how will the solubility of the salt compare with the answer that you have obtained in question 2.1? Explain you answer in a short sentence.Instead of using DI water to prepare your saturated solution, your lab partner used tap water, which in your region has a high Ca2+ content. It’s Taco Tuesday at the cafeteria and you are in a rush, so you decide to proceed with the experiment without making a new solution. How will this affect your solubility product constant calculations? Will it be higher than expected, lower than expected or remain the same? Explain.The compound lead(II) sulfate has a solubility of 4.824E-3 g/100mL at 25 degC.What is the molar solubility of this solution at saturation? 0.0002 mol/L What is the Ksp at 25 degC for lead(II) sulfate? What is the molar solubility of lead(II) sulfate in 0.28 M lead(II) nitrate ?
- Sodium chloride is added slowly to a solution that is 0.010 M in Cu+, Ag+, and Au+. Because solubility "rules" are generalizations, we don't use solubility rules when we have the specific Ksp data available. Instead, here, we can just use the Ksp value for CuCl which is 1.9 × 10–7, for AgCl is 1.6 × 10–10, and for AuCl is 2.0 × 10–13. Based on these specific Ksp values, which compound will precipitate first? All will precipitate at the same time. It cannot be determined. CuCl(s) AgCl(s) AuCl(s)Professor Acetico Acido has assigned the analysis of unknown organic compound samples to Al Cohol based on their solubility behavior. The summary of the solubility profile are tabulated below along with the possible structures of the samples. Identify each unknown sample by matching the respective solubility profile with the given structures. Briefly explain the reason for your answer.(a) If the molar solubility of Cu3(PO4)2 at 25 oC is 1.67e-08 mol/L, what is the Ksp at this temperature?Ksp = _______(b) It is found that 1.75e-06 g of Cu3(AsO4)2 dissolves per 100 mL of aqueous solution at 25 oC. Calculate the solubility-product constant for Cu3(AsO4)2.Ksp = _______(c) The Ksp of ScF3 at 25 oC is 5.81e-24. What is the molar solubility of ScF3?solubility = ______ mol/L