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- One of the products of petroleum refinery is naphtha where, benzene could beobtained via catalytic reforming of naphtha. The obtained benzene can potentiallyto react with Lewis acid to form new carbon-carbon bond. Propose the startingmaterial and stepwise mechanism to produce new chemical structure which consista formula molecule of C11H16.(a) Propose a reasonable synthesis for the formation of nonane from CH3CH2CH2I and any other organic/inorganic reagent. (b) Suggest three (3) different Grignard reactions leading to 2-phenyl-2-butanol.3. a. Write the complete reaction equation and give the name off all product (s) from the following reaction:i. bromination of phenolii. benzoic acid and ethylchloride in the presence of AlCl3b. Design the synthesis of two following compounds.i. m- chloropropiophenone from benzeneii. p-bromonitrobenzoic acid from toluene
- In an aqueous solution containing sodium bicarbonate, aniline reacts quickly withbromine to give 2,4,6-tribromoaniline. Nitration of aniline requires very strong conditions,however, and the yields (mostly m-nitroaniline) are poor.(a) What conditions are used for nitration, and what form of aniline is present under theseconditions?Stearolic acid, C18H32O2, yields stearic acid on catalytic hydrogenation and undergoes oxidative cleavage with ozone to yield nonanoic acid and nonanedioic acid. What is the structure of stearolic acid?Compound A has the molecular formula C14H25Br and was obtained by thereaction of sodium acetylide with 1,12-dibromododecane. On treatment ofcompound A with sodium amide, compound B (C14H24) was obtained. Ozonolysisof compound B gave the diacid HO2C(CH2)12CO2H. Catalytic hydrogenation ofcompound B over Lindlar palladium gave compound C (C14H26), andhydrogenation over platinum gave compound D (C14H28). Further, C yieldedO=CH(CH2)12CH=O on ozonolysis. Assign structures to compounds A through Dso as to be consistent with the observed transformations.
- Propose a synthesis of the anti-inflammatory drug Ibuprofen from benzene. Show all reagents and all intermediate structures. Assume that ortho and para isomers can be separatedA hydrocarbon (X), with the molecular formula: C8H14 is reduced in presence of sodium and liquid ammonia to give the only product (Y) with the molecular formula: C8H16. Compounds X and Y both resulting 2,5-dimethylhexane when treated with hydrogen and platinum catalyst (H2/Pt). As a result of the oxidative cleavage of compound Y (by using KMnO4 / H2SO4), a single carboxylic acid derivative with C4H8O2 molecular formula is formed. Again, as a result of the reaction of Y with perbenzoic acid, the chiral compound C8H14O is observed, but the reaction of compound Y with bromine gives the achiral C8H14Br2 as the product.a. Provide the structure of the hydrate of cyclopentanone. b. Provide the major organic product which results when pentanal is subjected to the following sequence of steps: 1. PhMgBr; 2. H3O+; 3. PCC.
- 1.Describe the ozonolysis of alkenes 2.one mole of a hydrocarbon(A) reacts with one mole of beomine giving a dibromo compound C5H10Br2.Substance A on treatment with cold dilute kMnO4 solution forms a compound C5C12O2(C5H12O2) on ozonolysis A,gives equimolar quantities of propanone and ethanol.Deduce the structure of substance A.Starting from indole, propose a synthesis of disubstituted indole E. More than one step is required. Outline reagents and conditions required to accomplish each step, identify key intermediates and discuss any point of selectivityBenzil reacts with 1,2-diaminobenzene to give a compound with molecular formua C20H14N2. Suggest a structure for this compound and write a reaction mechanism to show how it is formed. Do not give handwriting solution.