Suppose that you have a 1:1 mixture of compounds that is comprised of compound X and compound Y. You desire pure compound X and are planning a recrystallization to enhance the purity. Which solvent below is optimal for your recrystallization?      Ethanol (boiling point = 78 °C)   Solubility At   0  °C 100  °C Compound X 0.05 g/mL 0.20 g/mL Compound Y 0.02 g/mL 0.40 g/mL           Water (boiling point = 100 °C)   Solubility At   0  °C 100  °C Compound X 0.02 g/mL 0.05 g/mL Compound Y 0.01 g/mL 0.10 g/mL           Methanol (boiling point = 65 °C)   Solubility At   0  °C 65  °C Compound X 0.04 g/mL 0.10 g/mL Compound Y 0.02 g/mL 0.30 g/mL         Acetone (boiling point = 56 °C)   Solubility At   0  °C 56  °C Compound X 0.10 g/mL 0.50 g/mL Compound Y 0.20 g/mL 0.50 g/mL         Ethyl Acetate (boiling point = 77 °C)   Solubility At   0  °C 77  °C Compound X 0.10 g/mL 0.60 g/mL Compound Y 0.30 g/mL 0.60 g/mL

EBK A SMALL SCALE APPROACH TO ORGANIC L
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ISBN:9781305446021
Author:Lampman
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Chapter83: Simple Distillation
Section: Chapter Questions
Problem 2P
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Suppose that you have a 1:1 mixture of compounds that is comprised of compound X and compound Y. You desire pure compound and are planning a recrystallization to enhance the purity. Which solvent below is optimal for your recrystallization? 

   

Ethanol (boiling point = 78 °C)

  Solubility At
  0  °C 100  °C
Compound X 0.05 g/mL 0.20 g/mL
Compound Y 0.02 g/mL 0.40 g/mL

 

 

 

   

Water (boiling point = 100 °C)

  Solubility At
  0  °C 100  °C
Compound X 0.02 g/mL 0.05 g/mL
Compound Y 0.01 g/mL 0.10 g/mL

 

 

 

   

Methanol (boiling point = 65 °C)

  Solubility At
  0  °C 65  °C
Compound X 0.04 g/mL 0.10 g/mL
Compound Y 0.02 g/mL 0.30 g/mL

 

 

   

Acetone (boiling point = 56 °C)

  Solubility At
  0  °C 56  °C
Compound X 0.10 g/mL 0.50 g/mL
Compound Y 0.20 g/mL 0.50 g/mL

 

 

   

Ethyl Acetate (boiling point = 77 °C)

  Solubility At
  0  °C 77  °C
Compound X 0.10 g/mL 0.60 g/mL
Compound Y 0.30 g/mL 0.60 g/mL

 

 

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