Answered: Suppose the decomposition of nitrogen…

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 11.36PAE: The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a role in the formation of nitrogen dioxide in...

See similar textbooks

Related questions

Question

Suppose the formation of nitrosyl chloride proceeds by the following mechanism: step elementary reaction rate constant (g) (g) (g) (g) (g) (g) Suppose also ≫. That is, the first step is much faster than the second. Write the balanced chemical equation for the overall chemical reaction: Write the experimentally-observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. Express the rate constant k for the overall chemical reaction in terms of k1, k2, and (if necessary) the rate constants k-1 and k-2 for the reverse of the two elementary reactions in the mechanism.

Suppose the decomposition of nitrogen dioxide proceeds by the following mechanism:
step
elementary reaction
rate constant
1
NO₂(g)
→
NO(g) + O(g)
k₁
2 O(g) + NO₂(g) → O₂(g) + NO(g)
k₂
Suppose also k₁»k₂. That is, the first step is much faster than the second.
Write the balanced
0
chemical equation for the
overall chemical reaction:
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of K₁, K2,
and (if necessary) the rate
and I
for
Check
constants l
Explanation
rate = k
k =

Writing the rate law implied by a simple mechanism
NO₂(g) → NO(g) + V(g)
k₁
2 O(g) + NO₂(g) → O₂(g) + NO(g)
k₂
Suppose also k₁k₂. That is, the first step is much faster than the second.
Write the balanced
chemical equation for the
overall chemical reaction:
0
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should
not contain the
concentrations of any
intermediates.
Express the rate constant
k for the overall chemical
reaction in terms of K₁, K2,
and (if necessary) the rate
constants k-1 and k-2 for
the reverse of the two
elementary reactions in
the mechanism.
Explanation
Check
rate =
k =
0
k0

Expert Solution

Trending now

This is a popular solution!

Step by step

Solved in 4 steps with 4 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions