Table 5G.1 Solubility constants at 298.15 K Compound Formula K, Aluminium hydroxide Al(OH), 1.0 x 10-33 Antimony sulfide Sb,S, 1.7 x 10-93 Magnesium ammonium phosphate Barium carbonate BaCO, 8.1 x 10-9 MGNH,PO. 2.5 x 10-13 fluoride BaF, 1.7 x 10-6 M9CO, MgF, carbonate 1.0 x 10-5 sulfate BasO, 1.1 x 10-10 6.4 x 10-9 fluoride Bismuth sulfide Bi,S, CaCO, 1.0 x 10-97 hydroxide Mg(OH)2 1.1 x 10-11 Calcium carbonate 8.7 x 10-9 Mercury(l) chloride Hg,Cl, 1.3 x 10-18 fluoride CaF2 4.0 x 10-11 Hg,l2 HgS black: iodide 1.2 x 10-28 hydroxide Ca(OH)2 CaSO, 5.5 x 10-6 Mercury(ll) sulfide 1.6 x 10-62 sulfate 2.4 x 10-5 red: 1.4 x 10-53 Copper(I) bromide CuBr 4.2 x 10-8 Nickel(II) hydroxide Ni(OH), 6.5 x 10-18 chloride CuCl 1.0 x 10-6 Silver bromide 7.7 x 10-13 AgBr Ag,CO, AgCI A9OH iodide Cul 5.1 x 10-12 carbonate 6.2 x 10-12 sulfide Cu,S 2.0 x 10-47 chloride 1.6 x 10-10 Copper(II) iodate Cu(1O,)2 CuC,04 1.4 x 10-7 hydroxide 1.5 x 10-8 oxalate 2.9 x 10-8 iodide Agl 1.5 x 10-16 sulfide Cus 8.5 x 10 45 sulfide Ag,S Zn(OH), 6.3 x 10-51 Iron(II) hydroxide Fe(OH)2 1.6 x 10-14 Zinc hydroxide 2.0 x 10-17 sulfide Fes 6.3 x 10-18 sulfide ZnS 1.6 x 10-24 Iron(III) hydroxide Fe(OH), PbBr, 2.0 x 10-39 Lead(II) bromide 7.9 x 10-5 chloride PbCl, 1.6 x 10-5 PBF2 Pb(IO3)2 Pbl2 fluoride 3.7 x 10-8 iodate 2.6 x 10-13 iodide 1.4 x 10-8 sulfate 1.6 x 10-8 sulfide PbS 3.4 x 10-28

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter12: Chemical Equilibrium

Section12.3: Determining Equilibrium Constants

Problem 12.3PSP

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Question

Use the data given to estimate the molar solubilities of (a) BaSO₄, (b) Ag₂CO₃, (c) Fe(OH)₃, (d) Hg₂CI₂ in water.

Table 5G.1
Solubility constants at 298.15 K
Compound
Formula
K,
Aluminium hydroxide
Al(OH),
1.0 x 10-33
Antimony sulfide
Sb,S,
1.7 x 10-93
Magnesium ammonium
phosphate
Barium carbonate
BaCO,
8.1 x 10-9
MGNH,PO.
2.5 x 10-13
fluoride
BaF,
1.7 x 10-6
M9CO,
MgF,
carbonate
1.0 x 10-5
sulfate
BasO,
1.1 x 10-10
6.4 x 10-9
fluoride
Bismuth sulfide
Bi,S,
CaCO,
1.0 x 10-97
hydroxide
Mg(OH)2
1.1 x 10-11
Calcium carbonate
8.7 x 10-9
Mercury(l) chloride
Hg,Cl,
1.3 x 10-18
fluoride
CaF2
4.0 x 10-11
Hg,l2
HgS black:
iodide
1.2 x 10-28
hydroxide
Ca(OH)2
CaSO,
5.5 x 10-6
Mercury(ll) sulfide
1.6 x 10-62
sulfate
2.4 x 10-5
red:
1.4 x 10-53
Copper(I) bromide
CuBr
4.2 x 10-8
Nickel(II) hydroxide
Ni(OH),
6.5 x 10-18
chloride
CuCl
1.0 x 10-6
Silver bromide
7.7 x 10-13
AgBr
Ag,CO,
AgCI
A9OH
iodide
Cul
5.1 x 10-12
carbonate
6.2 x 10-12
sulfide
Cu,S
2.0 x 10-47
chloride
1.6 x 10-10
Copper(II) iodate
Cu(1O,)2
CuC,04
1.4 x 10-7
hydroxide
1.5 x 10-8
oxalate
2.9 x 10-8
iodide
Agl
1.5 x 10-16
sulfide
Cus
8.5 x 10 45
sulfide
Ag,S
Zn(OH),
6.3 x 10-51
Iron(II) hydroxide
Fe(OH)2
1.6 x 10-14
Zinc hydroxide
2.0 x 10-17
sulfide
Fes
6.3 x 10-18
sulfide
ZnS
1.6 x 10-24
Iron(III) hydroxide
Fe(OH),
PbBr,
2.0 x 10-39
Lead(II) bromide
7.9 x 10-5
chloride
PbCl,
1.6 x 10-5
PBF2
Pb(IO3)2
Pbl2
fluoride
3.7 x 10-8
iodate
2.6 x 10-13
iodide
1.4 x 10-8
sulfate
1.6 x 10-8
sulfide
PbS
3.4 x 10-28

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