Tell whether the stereogenic centers marked with an asterisk in the following structures have the R or the S configuration: CH, H. CO,H b. H2N- CH а. с. CH,OH (-)-serine (an amino acid found in proteins) H CH(CH3), (-)-menthone (found in peppermint) (+)-amphetamine (central nervous system stimulant)
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A: Given: m/z= 122. To find: The ion which has the given m/z value.
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Q: Draw the products of each reaction, and indicate the stereochemistry where appropriate.
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Q: The shrub ma huang (Section 5.4A) contains two biologically active stereoisomers—ephedrine and…
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Solved in 2 steps with 1 images
- Based on the image. What is 1. The anti-conformer of hexane in Newman projection. 2. The equivalent structure of LAM in sawhorse representation. 3.Which configuration (R or S) does the bottom asymmetric carbon have for the d seriesof sugars? Which configuration for the l series?Rank the following groups in order of decreasing priority. −CH=CH2, −CH3, −C≡CH, −H
- -Sketch the Fischer projection and make a model of each stereoisomer (R and S) of the alcohol 2-butanol, CH3CHOHCH2CH3. Also sketch the monosaccharide glyceraldehyde, HOCH2CHOHCHO. Prioritize the four groups attached to the stereocenter with 1 being the highest priority and 4 being the lowest priority.Identify pairs of molecules that represent enantiomers and diastereomers and identify each center stereogenic by writing R or S next to it.1) Are the molecules A and B... conformational isomers? Diastereomers? Enantiomers? Position isomers? Non-related? 2) What about the molecules B and C? 3) What about the molecules C and D?
- name the compund, and include the chilarty centers (R or S)?3b) (i) Using Fischer projection, draw all the stereoisomers of 3-chloro-2-hydroxypentanoic acid. ii) Assign the chiral centre(s) with R/S configurations in part (b)(i). Indicate which areenantiomers, diastereomers and meso compounds (if any).Present or Absent?a. Pi delocalization b. CH hyperconjugation c. Inductive effect
- Hypoglycin A, an amino acid derivative found in unripened lychee, is a compound that is acutely toxic and can lead to death when ingested in large amounts by undernourished children. Draw all possible stereoisomers for hypoglycin A, and give the R,S designation for each stereogenic center.Copy the structure and mark all stereocenters in each molecule and tell how many stereoisomers are possible for each Letter d, e and f only.Shown below is Streptomycin, an antibiotic medication used to treat a number of bacterial infections, including tuberculosis, plague, and endocarditis. Neomycin B has broad-spectrum antibacterial activity. Circle and label as many functional groups in these molecules as you can. Label each chiral carbon in Streptomycin. How many total stereoisomers exist for Streptomycin? Label each chiral carbon in Neomycin B. How many total stereoisomers exist for Neomycin B?