The addition of HBr to buta-1,3-diene results in 1,2-addition at cold temperatures and 1,4-addition at warm temperatures. If the 1,2-adduct is first formed at cold temperatures and then warmed up, the 1,4-adduct is formed, as shown here. Draw a mechanism for this H H Нeat Br Br 1,2-Adduct 1,4-Adduct isomerization.
The addition of HBr to buta-1,3-diene results in 1,2-addition at cold temperatures and 1,4-addition at warm temperatures. If the 1,2-adduct is first formed at cold temperatures and then warmed up, the 1,4-adduct is formed, as shown here. Draw a mechanism for this H H Нeat Br Br 1,2-Adduct 1,4-Adduct isomerization.
Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter23: Addition To A Carbonyl
Section: Chapter Questions
Problem 16CTQ
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